中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al2O3 catalyst with formic acid as a hydrogen donor

文献类型:期刊论文

作者Fu, Zhaolin1,2; Wang, Ze1,2; Lin, Weigang1,2,3; Song, Wenli1,2; Li, Songgeng1,2
刊名APPLIED CATALYSIS A-GENERAL
出版日期2017-10-25
卷号547页码:248-255
关键词Furfural Hydrogenation 2-methylfuran Hydrogen Donor Bimetallic Catalyst
ISSN号0926-860X
DOI10.1016/j.apcata.2017.09.011
文献子类Article
英文摘要

Conversion of furfural to 2-methylfuran over Cu/Al2O3, Ni/Al2O3 and Ni-Cu/Al2O3 catalysts were investigated with formic acid as a hydrogen donor. Ni/Al2O3 showed a high catalytic activity but a moderate selectivity to 2-methylfuran. Contrarily, Cu/Al2O3 showed a low catalytic activity but a high selectivity for carbonyl reduction. Over the bimetallic catalysts Ni-10%Cu/Al2O3, by increasing Ni content, more furfural was converted with the reduction of carbonyl primarily. The effect of reaction solvent and the fraction of formic acid were also studied. The result showed that isopropanol solvent could contribute to the formation of furfuryl alcohol with 96% selectivity through the transfer hydrogenation process. Formic acid could decompose to H-2 and CO2, remarkably promoting the hydrogenolysis of furfuryl alcohol to 2-methylfuran. Finally, 100% conversion and 92 mol% yield of 2-methylfuran could be obtained over 10%Ni-10%Cu/Al2O3. It was attributed to the synergic effect of Ni-Cu metals, with increased affinity for carbonyl reduction.

WOS关键词Situ Generated Hydrogen ; Ni-cu Catalysts ; Bio-oil ; Transfer Hydrogenation/hydrogenolysis ; Selective Hydrogenation ; Bimetallic Catalysts ; Phase Hydrogenation ; Pd Catalysts ; Reduction ; Glycerol
WOS研究方向Chemistry ; Environmental Sciences & Ecology
语种英语
WOS记录号WOS:000413607100028
资助机构National Natural Science Foundation of China(51476180)
源URL[http://ir.ipe.ac.cn/handle/122111/23298]  
专题过程工程研究所_多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sinodanish Coll, Beijing 100190, Peoples R China
3.Tech Univ Denmark, Dept Chem & Biochem Engn, Bldg 229, DK-2800 Lyngby, Denmark
推荐引用方式
GB/T 7714
Fu, Zhaolin,Wang, Ze,Lin, Weigang,et al. High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al2O3 catalyst with formic acid as a hydrogen donor[J]. APPLIED CATALYSIS A-GENERAL,2017,547:248-255.
APA Fu, Zhaolin,Wang, Ze,Lin, Weigang,Song, Wenli,&Li, Songgeng.(2017).High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al2O3 catalyst with formic acid as a hydrogen donor.APPLIED CATALYSIS A-GENERAL,547,248-255.
MLA Fu, Zhaolin,et al."High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al2O3 catalyst with formic acid as a hydrogen donor".APPLIED CATALYSIS A-GENERAL 547(2017):248-255.

入库方式: OAI收割

来源:过程工程研究所

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