Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst
文献类型：期刊论文
| 作者 | Gao, Junjie1; Zhang, Zailei2,3; An, Xuebin1; Zhang, Yi1 |
| 刊名 | APPLIED SURFACE SCIENCE
 |
| 出版日期 | 2017-12-31 |
| 卷号 | 426期号:DEC页码:714-724 |
| 关键词 | Cuo Sno2 Palladium Hollow |
| ISSN号 | 0169-4332 |
| DOI | 10.1016/j.apsusc.2017.07.234 |
| 文献子类 | Article |
| 英文摘要 | We designed and synthesized CuO/SnO2/Pd hollow microboxes, which was developed based on pre pared Cu2O cubes coated Pd nanosheets, controlled oxidation of CU2O/Pd, and etching of Cu2O/CuO/Pd by SnCl4 solution. The catalytic property of the Cu2O, Cu2O/SnO2, Cu2O/Pd/SnO2, Cu2O/Pd, Cu2O/CuO/Pd, CuO/SnO2/Pd, CuO, and commercial catalyst for dimethyldichlorosilane synthesis via the Rochow reaction was investigated. As compared to control samples and commercial catalyst, the prepared CuO/Pd/SnO2 hollow microboxes exhibited much higher silicon conversion (76.6%), which is related to the synergistic effect between CuO, Pd and SnO2, and to the distinct catalyst hollow structure which allows the efficient transportation of the reactant molecules to the active component. (C) 2017 Elsevier B.V. All rights reserved. |
| WOS关键词 | COPPER-BASED CATALYSTS ; DIMETHYLDICHLOROSILANE SYNTHESIS ; SOLVOTHERMAL SYNTHESIS ; ION BATTERIES ; MICROSPHERES ; PERFORMANCE ; NANOSTRUCTURES ; MICROPARTICLES ; OXIDATION ; SPHERES |
| WOS研究方向 | Chemistry ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000413658200079 |
| 资助机构 | National Natural Science Foundation of China(21006120 ; 51402299) |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/23398]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Beijing Inst Nanoenergy & Nanosyst, Beijing 100083, Peoples R China 3.Natl Ctr Nanosci & Technol NCNST, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Junjie,Zhang, Zailei,An, Xuebin,et al. Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst[J]. APPLIED SURFACE SCIENCE,2017,426(DEC):714-724. |
| APA | Gao, Junjie,Zhang, Zailei,An, Xuebin,&Zhang, Yi.(2017).Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst.APPLIED SURFACE SCIENCE,426(DEC),714-724. |
| MLA | Gao, Junjie,et al."Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst".APPLIED SURFACE SCIENCE 426.DEC(2017):714-724. |
入库方式： OAI收割
来源：过程工程研究所
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