One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids
文献类型：期刊论文
| 作者 | Yan, Dongxia1,2,3; Wang, Gongying1; Gao, Kai2,3; Lu, Xingmei2,3; Xin, Jiayu2; Zhang, Suojiang2 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2018-02-14 |
| 卷号 | 57期号:6页码:1851-1858 |
| ISSN号 | 0888-5885 |
| DOI | 10.1021/acs.iecr.7b04947 |
| 文献子类 | Article |
| 英文摘要 | 2,5-Furandicarboxylic acid (FDCA), which is usually produced from HMF catalyzed by noble metal catalysts, is an important biobased monomer for the degradable polymer polyethylene furandicarboxylate (PEF). In order to reduce the high costs of starting material and catalysts, a novel approach for the direct conversion of fructose into FDCA was developed by employing [Bmim]Cl as a solvent with non-noble metal (Fe-Zr-O) as a catalyst. Relatively high FDCA yield was obtained at full fructose conversion under optimal conditions. The kinetic study revealed that the oxidation of intermediate FFCA to FDCA possessed the highest activation energy, indicating this step is most affected by reaction temperature: Additionally, in the IL-promoted reaction system, other biomass sources, such as glucose, galactose, mannose, starch, and cellulose also can be directly converted, with lower FDCA yield compared with that of fructose due to the ineffective isomerization of aldohexoses into fructose. |
| WOS关键词 | SELECTIVE AEROBIC OXIDATION ; CATALYTIC CONVERSION ; RENEWABLE RESOURCES ; MILD CONDITIONS ; LEVULINIC ACID ; BIOMASS ; CHEMICALS ; GLUCOSE ; 2,5-DIFORMYLFURAN ; CHLORIDE |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000425473900009 |
| 资助机构 | National Key Technology R&D Program of China(2016YFB0301900) ; National Natural Science Foundation of China(21576269 ; Science & Technology Pillar Program of Sichuan Province(2015GZ0065) ; 21210006 ; 21506231) |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/23996]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ionic Liquids Clean Proc,Key Lab, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yan, Dongxia,Wang, Gongying,Gao, Kai,et al. One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2018,57(6):1851-1858. |
| APA | Yan, Dongxia,Wang, Gongying,Gao, Kai,Lu, Xingmei,Xin, Jiayu,&Zhang, Suojiang.(2018).One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,57(6),1851-1858. |
| MLA | Yan, Dongxia,et al."One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 57.6(2018):1851-1858. |
入库方式： OAI收割
来源：过程工程研究所
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