Studies on mild catalytic synthesis of methyl acrylate via one-step aldol reaction
文献类型：期刊论文
| 作者 | Wang, Gang1; Sararuk, Chidchon1; Li, Zeng-Xi1; Li, Chun-Shan1; Wang, Hui2; Zhang, Suo-Jiang2 |
| 刊名 | AICHE JOURNAL
 |
| 出版日期 | 2018-04-01 |
| 卷号 | 64期号:4页码:1359-1372 |
| 关键词 | Methyl Acrylate Aldol Reaction Mechanism Kinetic Thermodynamic |
| ISSN号 | 0001-1541 |
| DOI | 10.1002/aic.16022 |
| 文献子类 | Article |
| 英文摘要 | One-step catalytic synthesis of methyl acrylate from methyl acetate and trioxane, with 90.7% yield and 91.8% selectivity, was realized at 10-25 degrees 5. NMR analysis confirmed the ester enolization with generation of [i-Pr2EtN-H](+)[TfO](-) in the presence of i-Pr2EtN and Bu2BOTf, which was affected by solvent and base. The depolymerization of trioxane into formaldehyde was catalyzed by Bu2BOTf. The in-situ catalytic mechanism and efficiency of [i-Pr2EtN-H](+)[TfO](-) was determined and analyzed. Mechanism-based kinetic and thermodynamic studies were conducted for better understanding of this route. Also the primary process design and product separation simulation were carried out. (c) 2017 American Institute of Chemical Engineers AIChE J, 64: 1359-1372, 2018 |
| WOS关键词 | Acid ; Condensation ; Trioxane ; Temperature ; Propane ; Polymerization ; Decomposition |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000426489500017 |
| 资助机构 | National Natural Science Foundation of China(21676270 ; National Science Fundation for Excellent Young Scholars(21422607) ; National Key Projects for Fundamental Research and Development of China(2016YFB0601303) ; NSFC-Key Projects of Shanxi Coal Based Low Carbon Joint Foundation(U1610222) ; CAS/SAFEA International Partnership Program for Creative Research Teams ; 21576261) |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/24005]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Natl Key Lab Clean & Efficient Coking Technol, Inst Proc Engn,State Key Lab Multiphase Complex S, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Gang,Sararuk, Chidchon,Li, Zeng-Xi,et al. Studies on mild catalytic synthesis of methyl acrylate via one-step aldol reaction[J]. AICHE JOURNAL,2018,64(4):1359-1372. |
| APA | Wang, Gang,Sararuk, Chidchon,Li, Zeng-Xi,Li, Chun-Shan,Wang, Hui,&Zhang, Suo-Jiang.(2018).Studies on mild catalytic synthesis of methyl acrylate via one-step aldol reaction.AICHE JOURNAL,64(4),1359-1372. |
| MLA | Wang, Gang,et al."Studies on mild catalytic synthesis of methyl acrylate via one-step aldol reaction".AICHE JOURNAL 64.4(2018):1359-1372. |
入库方式： OAI收割
来源：过程工程研究所
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。