Efficient Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid by Magnetic Laccase Catalyst
文献类型：期刊论文
| 作者 | Wang, Ke-Feng1,2,4; Liu, Chun-lei3; Sui, Kun-yan1; Guo, Chen2; Liu, Chun-Zhao1,2 |
| 刊名 | CHEMBIOCHEM
 |
| 出版日期 | 2018-04-04 |
| 卷号 | 19期号:7页码:654-659 |
| 关键词 | Enzyme Catalysis Furandicarboxylic Acid Hydroxymethylfurfural Immobilization Laccase |
| ISSN号 | 1439-4227 |
| DOI | 10.1002/cbic.201800008 |
| 文献子类 | Article |
| 英文摘要 | 2,5-Furandicarboxylic acid (FDCA) is a bio-based platform chemical for the production of polyethylene furanoate (PEF) and other valuable furanic chemicals. A magnetic laccase catalyst with (2,2,6,6-tetramethyl-piperidin-1-yl)oxyl (TEMPO) as the mediator has the remarkable capability of oxidizing 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). Under optimal reaction conditions, a quantitative yield (90.2%) of FDCA with complete HMF conversion was obtained after 96h of reaction. More importantly, the magnetic laccase catalyst exhibited good recyclability and stability, maintaining 84.8% of its original activity following six reuse cycles. This is the first report on the efficient catalytic oxidation of HMF to FDCA by using an immobilized enzyme catalyst. |
| WOS关键词 | MESOPOROUS SILICA NANOPARTICLES ; AEROBIC OXIDATION ; CARBOXYLIC-ACIDS ; IMMOBILIZATION ; PERFORMANCE ; BIOMASS ; PURIFICATION ; FABRICATION ; CONVERSION ; OXIDASE |
| WOS研究方向 | Biochemistry & Molecular Biology ; Pharmacology & Pharmacy |
| 语种 | 英语 |
| WOS记录号 | WOS:000429412800002 |
| 资助机构 | National Natural Science Foundation of China(21476242) ; National Key Technology Research and Development Program of China(2015BAK45B01) ; National Basic Research Program (973 Program) of China(2013CB733600) ; Key Research and Development Project of Shandong Province(2016GGX102005) |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/24156]  |
| 专题 | 过程工程研究所_生化工程国家重点实验室 |
| 作者单位 | 1.Qingdao Univ, Inst Biochem Engn, Collaborat Innovat Ctr Marine Biomass Fibers Mat, Sch Mat Sci & Engn, Qingdao 266071, Peoples R China 2.Chinese Acad Sci, State Key Lab Biochem Engn, Inst Proc Engn, Beijing 100190, Peoples R China 3.Qingdao Cent Hosp, Dept Urol, Qingdao 266042, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Ke-Feng,Liu, Chun-lei,Sui, Kun-yan,et al. Efficient Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid by Magnetic Laccase Catalyst[J]. CHEMBIOCHEM,2018,19(7):654-659. |
| APA | Wang, Ke-Feng,Liu, Chun-lei,Sui, Kun-yan,Guo, Chen,&Liu, Chun-Zhao.(2018).Efficient Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid by Magnetic Laccase Catalyst.CHEMBIOCHEM,19(7),654-659. |
| MLA | Wang, Ke-Feng,et al."Efficient Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid by Magnetic Laccase Catalyst".CHEMBIOCHEM 19.7(2018):654-659. |
入库方式： OAI收割
来源：过程工程研究所
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