Efficient extraction and enrichment of rare earth from diluent aqueous solution by organic hollow sphere
文献类型:期刊论文
作者 | Xiao, Chuanxu1,2; Huang, Kun1; Cao, Wenjuan1,2; Dong, Tingting1,2; Li, Min1,2; Liu, Huizhou1 |
刊名 | CHEMICAL ENGINEERING RESEARCH & DESIGN
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出版日期 | 2018-04-01 |
卷号 | 132页码:19-27 |
关键词 | Rare Earths Low Concentration Enrichment Solvent Extraction Organic Hollow Sphere |
ISSN号 | 0263-8762 |
DOI | 10.1016/j.cherd.2018.01.001 |
文献子类 | Article |
英文摘要 | Extraction of rare earths from leach aqueous solution by conventional chemical precipitation brings severe amino-nitrogen pollution. In this work, a novel method was developed by organic hollow sphere to extract and enrich Er(III), a model middle-heavy rare earth ion, from diluent aqueous solution. The organic hollow sphere is a core-shell structure, in which the core is composed of gas phase and the shell is a thin layer of organic extractant. The effects of flow rates of gas phase and/or organic extractant on Er(III) extraction rate were investigated. The results demonstrated that the flow rate of gas phase played more important role than that of organic extractant in the extraction rate of Er(III). Accompanied by the achievement of a large volume ratio (1000:1) of aqueous solution to organic extractant, the enrichment ratio (100) of the rare-earth ions could reach a significant level, which is much higher than that by conventional methods. The lower flow rate of organic extractant is more beneficial to Er(III) enrichment. It demonstrates that the newly developed extraction technique in this work is promising, and as a result the development of organic hollow sphere extraction process for the recovery of REs is straightforwardly envisaged. (C) 2018 Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved. |
WOS关键词 | PULSED DISC ; COLUMN |
WOS研究方向 | Engineering |
语种 | 英语 |
WOS记录号 | WOS:000430522300003 |
资助机构 | National Natural Science Foundation of China(51574213 ; Key Project of Chinese National Programs for Fundamental Research and Development (973 Programs)(2012CBA01203 ; 51074150) ; 2013CB632602) |
源URL | [http://ir.ipe.ac.cn/handle/122111/24430] ![]() |
专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 10049, Peoples R China |
推荐引用方式 GB/T 7714 | Xiao, Chuanxu,Huang, Kun,Cao, Wenjuan,et al. Efficient extraction and enrichment of rare earth from diluent aqueous solution by organic hollow sphere[J]. CHEMICAL ENGINEERING RESEARCH & DESIGN,2018,132:19-27. |
APA | Xiao, Chuanxu,Huang, Kun,Cao, Wenjuan,Dong, Tingting,Li, Min,&Liu, Huizhou.(2018).Efficient extraction and enrichment of rare earth from diluent aqueous solution by organic hollow sphere.CHEMICAL ENGINEERING RESEARCH & DESIGN,132,19-27. |
MLA | Xiao, Chuanxu,et al."Efficient extraction and enrichment of rare earth from diluent aqueous solution by organic hollow sphere".CHEMICAL ENGINEERING RESEARCH & DESIGN 132(2018):19-27. |
入库方式: OAI收割
来源:过程工程研究所
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