Size and Morphology Controlled Synthesis of Boehmite Nanoplates and Crystal Growth Mechanisms
文献类型：期刊论文
| 作者 | Zhang, Xin1; Cui, Wenwen1,2,3; Page, Katharine L.4; Pearce, Carolyn, I1; Bowden, Mark E.1; Graham, Trent R.5; Shen, Zhizhang1; Li, Ping2; Wang, Zheming1; Kerisit, Sebastien1 |
| 刊名 | CRYSTAL GROWTH & DESIGN
 |
| 出版日期 | 2018-06-01 |
| 卷号 | 18期号:6页码:3596-3606 |
| ISSN号 | 1528-7483 |
| DOI | 10.1021/acs.cgd.8b00394 |
| 英文摘要 | The aluminum oxyhydroxide boehmite is an important crystalline phase in nature and industry. We report development of a flexible additive-free hydrothermal synthesis method to prepare high quality boehmite nanoplates with sizes ranging from under 20 nm 5 mu m to via using hydrated alumina gels and aluminum hydroxide amorphous powders as precursors. The size and morphology of the boehmite nanoplates was systematically varied between hexagonal and rhombic by adjusting precursor concentrations, pH, and the synthesis temperature, due to face-specific effects. The transformation mechanism is consistent with dissolution and reprecipitation, and involves transitory initial appearance of metastable gibbsite that is later consumed upon nucleation of boehmite. Detailed X-ray pair distribution characterization of the solids over time showed similarities in short-range order that suggest linkages in local chemistry and bonding topology between the precursors and product boehmite, yet also that precursor-specific differences in long-range order appear to manifest subtle changes in resulting boehmite characteristics, suggesting that the rate and extent of water release or differences in the resulting solubilized aluminate speciation lead to slightly different polymerization and condensation pathways. The findings suggest that, during dissolution of the precursor, precursor-specific dehydration or solution speciation could be important aspects of the transformation impacting the molecular-level details of boehmite nucleation and growth. |
| WOS关键词 | RAY-ABSORPTION SPECTROSCOPY ; GAMMA-ALOOH NANORODS ; HYDROTHERMAL SYNTHESIS ; OXIDE NANOPARTICLES ; ALUMINA ; GIBBSITE ; CRYSTALLIZATION ; NANOFLAKES ; STABILITY ; SULFATE |
| 资助项目 | IDREAM (Interfacial Dynamics in Radioactive Environments and Materials), an Energy Frontier Research Center - U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences (BES) ; DOE Office of Science, BES[DE-AC02-06CH11357] ; DOE Office of Science User Facility[DE-AC02-05CH11231] ; DOE Office of Biological and Environmental Research ; DOE[DE-AC05-76RL0-18300] |
| WOS研究方向 | Chemistry ; Crystallography ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000434894100039 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | IDREAM (Interfacial Dynamics in Radioactive Environments and Materials), an Energy Frontier Research Center - U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences (BES) ; DOE Office of Science, BES ; DOE Office of Science User Facility ; DOE Office of Biological and Environmental Research ; DOE |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/25023]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 通讯作者 | Zhang, Xin; Rosso, Kevin M. |
| 作者单位 | 1.Pacific Northwest Natl Lab, Richland, WA 99354 USA 2.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Oak Ridge Natl Lab, Neutron Scattering Div, POB 2009, Oak Ridge, TN 37830 USA 5.Washington State Univ, Voiland Sch Chem & Biol Engn, Pullman, WA 99163 USA 6.Adv Light Source, Berkeley, CA 94720 USA 7.Washington State Univ, Dept Chem, Pullman, WA 99164 USA |
| 推荐引用方式 GB/T 7714 | Zhang, Xin,Cui, Wenwen,Page, Katharine L.,et al. Size and Morphology Controlled Synthesis of Boehmite Nanoplates and Crystal Growth Mechanisms[J]. CRYSTAL GROWTH & DESIGN,2018,18(6):3596-3606. |
| APA | Zhang, Xin.,Cui, Wenwen.,Page, Katharine L..,Pearce, Carolyn, I.,Bowden, Mark E..,...&Rosso, Kevin M..(2018).Size and Morphology Controlled Synthesis of Boehmite Nanoplates and Crystal Growth Mechanisms.CRYSTAL GROWTH & DESIGN,18(6),3596-3606. |
| MLA | Zhang, Xin,et al."Size and Morphology Controlled Synthesis of Boehmite Nanoplates and Crystal Growth Mechanisms".CRYSTAL GROWTH & DESIGN 18.6(2018):3596-3606. |
入库方式： OAI收割
来源：过程工程研究所
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