Low temperature selective catalytic reduction of NOX with NH3 by activated coke loaded with FexCoyCezOm: The enhanced activity, mechanism and kinetics
文献类型:期刊论文
作者 | Lu, Pei1,2; Li, Rui1,2; Xing, Yi1,2; Li, Yuran3; Zhu, Tingyu3; Yue, Huifang1,2; Wu, Wanrong1,2 |
刊名 | FUEL
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出版日期 | 2018-12-01 |
卷号 | 233页码:188-199 |
关键词 | Activated Coke Low-temperature Scr Nox The Enhanced Activity Mechanism And Kinetics |
ISSN号 | 0016-2361 |
DOI | 10.1016/j.fuel.2018.05.076 |
英文摘要 | The existing catalysts based on activated coke had generally poor denitration performance at low temperature, which could not meet the urgent needs of power plants and steel enterprises. In this study, activated coke loaded with FexCoyCezOm was prepared by incipient wetness impregnation method and employed to remove NOx at 100-350 degrees C in simulated flue gas. 3% Fe0.6Co0.2Ce0.2O1.57/AC catalyst exhibited highest NOx removal efficiency as it had more than 70% NOx conversion rate at 100 degrees C and achieved more than 90% denitrition efficiency at 250-350 degrees C. The catalyst also showed stable catalytic performance and good resistance to H2O or/and SO2 at 250 degrees C. Based on the results of Brunauer-Emmett-Teller (BET), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), temperature programmed desorption (TPD), temperature programmed reduction (TPR) and Fourier transform infrared spectroscopy (FTIR), the enhanced performance could be attributed to the co-participation of Fe, Co and Ce species with different valence states, the high concentration of chemisorbed oxygen, highly dispersed active components, the increase of weak acid sites, good redox properties of metallic oxides and abundant founctional groups on the catalyts surface. Finally, the possible mechanism and kinetics of NOx removal over FexCoyCezOm/AC catalyst were discussed in detail, which revealed that the enhanced performance was resulted from the increased active sites and the redox cycle among Fe, Co and Ce. |
WOS关键词 | Simulated Flue-gas ; Dispersed Mnox/sapo-34 Catalyst ; Elemental Mercury ; Simultaneous Removal ; Sulfur Resistance ; Nitrogen-oxides ; So2 Resistance ; Performance ; Nh3-scr ; Scr |
资助项目 | National Key R&D Program of China[2017YFC0210303] ; Beijing Science and Technology Project[D161100004516001] ; Open fund of National Engineering Laboratory for Mobile Source Emission Control Technology[NELMS2017A14] ; Fundamental Research Funds for the Central Universities |
WOS研究方向 | Energy & Fuels ; Engineering |
语种 | 英语 |
WOS记录号 | WOS:000441893200020 |
出版者 | ELSEVIER SCI LTD |
资助机构 | National Key R&D Program of China ; Beijing Science and Technology Project ; Open fund of National Engineering Laboratory for Mobile Source Emission Control Technology ; Fundamental Research Funds for the Central Universities |
源URL | [http://ir.ipe.ac.cn/handle/122111/25938] ![]() |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Xing, Yi |
作者单位 | 1.Univ Sci & Technol Beijing, Sch Energy & Environm Engn, Beijing 100083, Peoples R China 2.Univ Sci & Technol Beijing, Beijing Key Lab Resource Oriented Treatment Ind P, Beijing 100083, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Cleaner Hydromet Prod Technol, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Lu, Pei,Li, Rui,Xing, Yi,et al. Low temperature selective catalytic reduction of NOX with NH3 by activated coke loaded with FexCoyCezOm: The enhanced activity, mechanism and kinetics[J]. FUEL,2018,233:188-199. |
APA | Lu, Pei.,Li, Rui.,Xing, Yi.,Li, Yuran.,Zhu, Tingyu.,...&Wu, Wanrong.(2018).Low temperature selective catalytic reduction of NOX with NH3 by activated coke loaded with FexCoyCezOm: The enhanced activity, mechanism and kinetics.FUEL,233,188-199. |
MLA | Lu, Pei,et al."Low temperature selective catalytic reduction of NOX with NH3 by activated coke loaded with FexCoyCezOm: The enhanced activity, mechanism and kinetics".FUEL 233(2018):188-199. |
入库方式: OAI收割
来源:过程工程研究所
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