Highly Porous Nitrogen- and Phosphorus-Codoped Graphene: An Outstanding Support for Pd Catalysts to Oxidize 5-Hydroxymethylfurfural into 2,5-Furandicarboxylic Acid
文献类型：期刊论文
| 作者 | Zhang, Yajie; Chen, Chunlin; Li, Xingtao; Wang, Lingchen; Liang, Ting; Wang, Lei; Zhang, Jian |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2017 |
| 卷号 | 5期号:12页码:11300-11306 |
| ISSN号 | 2168-0485 |
| 英文摘要 | The oxidation of 5-hydroxylmethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) is a sustainable and promising route to bioderived aromatic polyesters. So far, the design of catalyst has been restricted by the unclear working mechanism, and thus most of the supported noble metal catalysts cannot provide a remarkable reaction rate under atmospheric pressures and room temperature. Here we report a new mechanistic insight into the structure performance correlation of graphene-supported Pd catalysts. It is demonstrated that a new kind of highly porous nitrogen- and phosphorus-codoped graphene sheets (HPGSs) will enhance the fraction of surface Pd2+ species, which plays a determining role to reduce the activation energies of both HMF conversion and FDCA formation. Such a support effect may assist in developing highly active catalysts for FDCA synthesis under mild conditions. |
| 公开日期 | 2017-12-25 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/13479]  |
| 专题 | 2017专题 |
| 推荐引用方式 GB/T 7714 | Zhang, Yajie,Chen, Chunlin,Li, Xingtao,et al. Highly Porous Nitrogen- and Phosphorus-Codoped Graphene: An Outstanding Support for Pd Catalysts to Oxidize 5-Hydroxymethylfurfural into 2,5-Furandicarboxylic Acid[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2017,5(12):11300-11306. |
| APA | Zhang, Yajie.,Chen, Chunlin.,Li, Xingtao.,Wang, Lingchen.,Liang, Ting.,...&Zhang, Jian.(2017).Highly Porous Nitrogen- and Phosphorus-Codoped Graphene: An Outstanding Support for Pd Catalysts to Oxidize 5-Hydroxymethylfurfural into 2,5-Furandicarboxylic Acid.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,5(12),11300-11306. |
| MLA | Zhang, Yajie,et al."Highly Porous Nitrogen- and Phosphorus-Codoped Graphene: An Outstanding Support for Pd Catalysts to Oxidize 5-Hydroxymethylfurfural into 2,5-Furandicarboxylic Acid".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 5.12(2017):11300-11306. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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