Stabilizing Li/electrolyte interface with a transplantable protective layer based on nanoscale LiF domains
文献类型：期刊论文
| 作者 | Peng, Zhe; Zhao, Ning; Zhang, Zhenggang; Wan, Hao; Lin, Huan; Liu, Meng; Shen, Cai; He, Haiyong; Guo, Xiangxin; Zhang, Ji-Guang |
| 刊名 | NANO ENERGY
 |
| 出版日期 | 2017 |
| 卷号 | 39页码:662-672 |
| ISSN号 | 2211-2855 |
| 英文摘要 | Although Li metal has been regarded as one of the most promising anode materials, an unstable Li/electrolyte interface during the cycling process seriously limits its practical application in rechargeable batteries. Herein, we report a transplantable LiF-rich layer (TLL) that can suppress the side reactions between electrolyte and lithium metal. This peelable layer cross-linked by nanoscale LiF domains is obtained by electrochemically reducing NiF2 electrodes and could be used to protect Li metal anodes. Cu-Li cells using the TLL protection can operate for more than 300 cycles with a Coulombic efficiency as high as similar to 98% in carbonate-based electrolytes. In Li-LiFePO4 cells, lithium metal with a TLL still looks shiny after 1000 cycles (similar to 6 months) in contrast to the black surface of bare lithium foil after similar to 500 cycles (similar to 3 months). These results clearly demonstrate that the TLL could greatly limit the side reactions between lithium metal and the carbonate-based electrolytes, and may enable long-term stable operation of Li metal batteries. |
| 公开日期 | 2017-12-25 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/13641]  |
| 专题 | 2017专题 |
| 推荐引用方式 GB/T 7714 | Peng, Zhe,Zhao, Ning,Zhang, Zhenggang,et al. Stabilizing Li/electrolyte interface with a transplantable protective layer based on nanoscale LiF domains[J]. NANO ENERGY,2017,39:662-672. |
| APA | Peng, Zhe.,Zhao, Ning.,Zhang, Zhenggang.,Wan, Hao.,Lin, Huan.,...&Wang, Deyu.(2017).Stabilizing Li/electrolyte interface with a transplantable protective layer based on nanoscale LiF domains.NANO ENERGY,39,662-672. |
| MLA | Peng, Zhe,et al."Stabilizing Li/electrolyte interface with a transplantable protective layer based on nanoscale LiF domains".NANO ENERGY 39(2017):662-672. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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