An amorphous FeMoS4 nanorod array toward efficient hydrogen evolution electrocatalysis under neutral conditions
文献类型:期刊论文
作者 | Ren, Xiang; Wang, Weiyi; Ge, Ruixiang; Hao, Shuai; Qu, Fengli; Du, Gu; Asiri, Abdullah M.; Wei, Qin; Chen, Liang; Sun, Xuping |
刊名 | CHEMICAL COMMUNICATIONS
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出版日期 | 2017 |
卷号 | 53期号:64页码:9000-9003 |
ISSN号 | 1359-7345 |
英文摘要 | It is highly attractive to develop efficient hydrogen-evolving electrocatalysts under neutral conditions. In this communication, we report an amorphous FeMoS4 nanorod array on carbon cloth (FeMoS4 NRA/CC) prepared by hydrothermal treatment of an FeOOH nanorod array on carbon cloth (FeOOH NRA/CC) in (NH4)(2)MoS4 solution. As a 3D electrode for hydrogen evolution electrocatalysis, this FeMoS4 NRA/CC demonstrates superior catalytic activity and strong longterm electrochemical durability in 1.0 M phosphate buffered saline (pH:7). It needs an overpotential of 204 mV to drive a geometrical current density of 10 mA cm(-2), which is 450 mV less than that for FeOOH NRA/CC. Density functional theory calculations suggest that FeMoS4 has a more favourable hydrogen adsorption free energy than FeOOH. |
公开日期 | 2017-12-25 |
源URL | [http://ir.nimte.ac.cn/handle/174433/13676] ![]() |
专题 | 2017专题 |
推荐引用方式 GB/T 7714 | Ren, Xiang,Wang, Weiyi,Ge, Ruixiang,et al. An amorphous FeMoS4 nanorod array toward efficient hydrogen evolution electrocatalysis under neutral conditions[J]. CHEMICAL COMMUNICATIONS,2017,53(64):9000-9003. |
APA | Ren, Xiang.,Wang, Weiyi.,Ge, Ruixiang.,Hao, Shuai.,Qu, Fengli.,...&Sun, Xuping.(2017).An amorphous FeMoS4 nanorod array toward efficient hydrogen evolution electrocatalysis under neutral conditions.CHEMICAL COMMUNICATIONS,53(64),9000-9003. |
MLA | Ren, Xiang,et al."An amorphous FeMoS4 nanorod array toward efficient hydrogen evolution electrocatalysis under neutral conditions".CHEMICAL COMMUNICATIONS 53.64(2017):9000-9003. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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