Designing bio-based plasticizers: Effect of alkyl chain length on plasticization properties of isosorbide diesters in PVC blends
文献类型：期刊论文
| 作者 | Yang, Yong; Huang, Juncheng; Zhang, Ruoyu; Zhu, Jin |
| 刊名 | MATERIALS & DESIGN
 |
| 出版日期 | 2017 |
| 卷号 | 126页码:29-36 |
| ISSN号 | 0264-1275 |
| 英文摘要 | A series of bio-based plasticizers based on isosorbide, a renewable monomer derived from glucose, were successfully synthesized. The chemical structures of the synthesized isosorbide diesters with different alkyl chain length were confirmed by FTIR and 1H NMR. The influence of varying alkyl chain length on thermal and mechanical properties of isosorbide diesters in poly(vinyl chloride) (PVC) was investigated in detail. It was found that the plasticizing efficiency of isosorbide diester decreased as the alkyl chain length increased, reflecting on the gradually increased Tg and the decreased elongation at break of PVC blend. However, the longer alkyl chain length of isosorbide diester improved the thermal stability of PVC blend and simultaneously depressed its volatility from PVC. Besides, the bio-based isosorbide diesters rivaled those petro-based phthalates, and they could be potential candidates to replace phthalates in the future industry. |
| 公开日期 | 2017-12-25 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/13725]  |
| 专题 | 2017专题 |
| 推荐引用方式 GB/T 7714 | Yang, Yong,Huang, Juncheng,Zhang, Ruoyu,et al. Designing bio-based plasticizers: Effect of alkyl chain length on plasticization properties of isosorbide diesters in PVC blends[J]. MATERIALS & DESIGN,2017,126:29-36. |
| APA | Yang, Yong,Huang, Juncheng,Zhang, Ruoyu,&Zhu, Jin.(2017).Designing bio-based plasticizers: Effect of alkyl chain length on plasticization properties of isosorbide diesters in PVC blends.MATERIALS & DESIGN,126,29-36. |
| MLA | Yang, Yong,et al."Designing bio-based plasticizers: Effect of alkyl chain length on plasticization properties of isosorbide diesters in PVC blends".MATERIALS & DESIGN 126(2017):29-36. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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