中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Recyclable polybutadiene elastomer based on dynamic imine bond

文献类型:期刊论文

作者Xu, Jian; Liu, Chenyang; Zhao, Ning; Zhang, Huan; Wang, Dong; Zhang, Jiawei; Liu, Wenxing; Li, Pengchong; Liu, Jiajian
刊名JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
出版日期2017
卷号55期号:12页码:2011-2018
ISSN号0887-624X
英文摘要Catalyst-free recyclable polybutadiene (PB) elastomer cross-linked by dynamic imine bonds is prepared by the reaction between amine functionalized PB and aldehyde cross-linkers. The dynamic nature of imine bond is investigated by rheometry and creep-recovery experiments. The cross-linking degrees are regulated by incorporating different amount of aldehyde, and their influence on the cross-linked elastomers is investigated in detail. The temperature-induced imine exchange reactions enable recycling of the cross-linked PB elastomers and their mechanical properties are almost unchanged after several cycles. It is important to note that the elastomers also show excellent solvent resistance even at high temperature. The good mechanical properties, solvent resistance and recycling ability of the resultant PB elastomer demonstrate the superiority of the imine bonds in the design of recyclable polymers. (c) 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017, 55, 2011-2018
公开日期2017-12-25
源URL[http://ir.nimte.ac.cn/handle/174433/13769]  
专题2017专题
推荐引用方式
GB/T 7714
Xu, Jian,Liu, Chenyang,Zhao, Ning,et al. Recyclable polybutadiene elastomer based on dynamic imine bond[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2017,55(12):2011-2018.
APA Xu, Jian.,Liu, Chenyang.,Zhao, Ning.,Zhang, Huan.,Wang, Dong.,...&Liu, Jiajian.(2017).Recyclable polybutadiene elastomer based on dynamic imine bond.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,55(12),2011-2018.
MLA Xu, Jian,et al."Recyclable polybutadiene elastomer based on dynamic imine bond".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 55.12(2017):2011-2018.

入库方式: OAI收割

来源:宁波材料技术与工程研究所

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