Hexahydro-s-triazine: A Trial for Acid-Degradable Epoxy Resins with High Performance
文献类型：期刊论文
| 作者 | You, Shusen; Dai, Jinyue; Jia, Zhen; Zhu, Jin; Liu, Xiaoqing; Ma, Songqi |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2017 |
| 卷号 | 5期号:6页码:4683-4689 |
| ISSN号 | 2168-0485 |
| 英文摘要 | Hexahydro-s-triazine (HT) derivatives are acid sensitive compounds. 4,4',4 ''-(1,3,5-Hexahydro-s-triazine-1,3,5-NH, triy1) tris(N-(2-aminoethyl) benzamide) (HT -A) bearing three amino groups was synthesized as a curing agent to prepare the acid -degradable epoxy resin. The chemical structures of HT -A and its precursor were confirmed by 'H NMR and C-13 NMR. The synthesized HT -A, as well as the commercialized 4,4'-diaminodiphenylmethane (DDM) (for use as the control) were used to cure diglycidyl ether of bisphenol A (DGEBA), respectively. The property examinations performed by dynamic mechanical analysis (DMA), differential scanning calorimeter (DSC), thermogravimetric analysis (TGA), and tensile test demonstrated that the HT -A -cured epoxy presented high thermal and mechanical properties which were comparable with those of the DDM cured one. Meanwhile, degradation investigation indicated that the HT -A -cured epoxy could be controllably degraded with strong acid stimuli. Thus, HT -A has a great potential to produce recyclable thermosets with satisfactory properties. |
| 公开日期 | 2017-12-25 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/13810]  |
| 专题 | 2017专题 |
| 推荐引用方式 GB/T 7714 | You, Shusen,Dai, Jinyue,Jia, Zhen,et al. Hexahydro-s-triazine: A Trial for Acid-Degradable Epoxy Resins with High Performance[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2017,5(6):4683-4689. |
| APA | You, Shusen,Dai, Jinyue,Jia, Zhen,Zhu, Jin,Liu, Xiaoqing,&Ma, Songqi.(2017).Hexahydro-s-triazine: A Trial for Acid-Degradable Epoxy Resins with High Performance.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,5(6),4683-4689. |
| MLA | You, Shusen,et al."Hexahydro-s-triazine: A Trial for Acid-Degradable Epoxy Resins with High Performance".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 5.6(2017):4683-4689. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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