中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Pore-neck resistance to light gases in a microporous BTESE-derived silica: A comparison of membrane and xerogel powder

文献类型:期刊论文

作者Gu, Xuehong; Chen, Liang; Gao, Xuechao; Ji, Guozhao; Peng, Li
刊名JOURNAL OF MEMBRANE SCIENCE
出版日期2017
卷号531页码:36-46
ISSN号0376-7388
英文摘要A supported membrane and a xerogel derived from 1,2-bis(triethoxysilyl)ethane (BTESE) under the same conditions were characterized by a gas uptake technique and membrane permeation method, respectively, to investigate the transport mechanism inside the pores. The results indicated that the transport in both materials was governed by repulsive necks, with more adsorptive gases experiencing stronger restrictions. Furthermore, on the basis of a comparison between the two samples, the similarity of activation energies for spherical gases provided positive evidence for the commonly used assumption of pore network equivalence between xerogels and membranes derived under the same conditions. Finally, the neck dimensions in both materials were evaluated by the GT-based model, and a mean value of approximately 2.90 angstrom (center-to-center distance) was obtained.
公开日期2017-12-25
源URL[http://ir.nimte.ac.cn/handle/174433/13814]  
专题2017专题
推荐引用方式
GB/T 7714
Gu, Xuehong,Chen, Liang,Gao, Xuechao,et al. Pore-neck resistance to light gases in a microporous BTESE-derived silica: A comparison of membrane and xerogel powder[J]. JOURNAL OF MEMBRANE SCIENCE,2017,531:36-46.
APA Gu, Xuehong,Chen, Liang,Gao, Xuechao,Ji, Guozhao,&Peng, Li.(2017).Pore-neck resistance to light gases in a microporous BTESE-derived silica: A comparison of membrane and xerogel powder.JOURNAL OF MEMBRANE SCIENCE,531,36-46.
MLA Gu, Xuehong,et al."Pore-neck resistance to light gases in a microporous BTESE-derived silica: A comparison of membrane and xerogel powder".JOURNAL OF MEMBRANE SCIENCE 531(2017):36-46.

入库方式: OAI收割

来源:宁波材料技术与工程研究所

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