In situ formation of a 3D core/shell structured Ni3N@Ni-Bi nanosheet array: an efficient non-noble-metal bifunctional electrocatalyst toward full water splitting under near-neutral conditions
文献类型：期刊论文
| 作者 | Ge, Ruixiang; Du, Gu; Asiri, Abdullah M.; Sun, Xuping; Chen, Liang; Xie, Lisi; Qu, Fengli; Liu, Zhiang; Ren, Xiang; Hao, Shuai |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2017 |
| 卷号 | 5期号:17页码:7806-7810 |
| ISSN号 | 2050-7488 |
| 英文摘要 | It is of great importance but still remains a key challenge to develop non-noble-metal bifunctional catalysts for efficient full water splitting undermild pH conditions. In this communication, we report the in situ electrochemical development of an ultrathin Ni-Bi layer on a metallic Ni3N nanosheet array supported on a Ti mesh (Ni3N@Ni-Bi NS/Ti) as a durable 3D core/shell structured nanoarray electrocatalyst for water oxidation at near-neutral pH. The Ni3N@Ni-Bi NS/Ti demands overpotentials of 405 and 382mV to deliver a geometrical catalytic current density of 10 mA cm(-2) in 0.1 and 0.5 M K-Bi (pH: 9.2), respectively, superior in activity to Ni3N NS/Ti and most reported non-precious metal catalysts under benign conditions. It also performs efficiently for the hydrogen evolution reaction requiring an overpotential of 265 mV for 10 mA cm(-2) and its two-electrode electrolyser affords 10 mA cm(-2) at a cell voltage of 1.95 V in 0.5 M K-Bi at 25 degrees C. |
| 公开日期 | 2017-12-25 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/13836]  |
| 专题 | 2017专题 |
| 推荐引用方式 GB/T 7714 | Ge, Ruixiang,Du, Gu,Asiri, Abdullah M.,et al. In situ formation of a 3D core/shell structured Ni3N@Ni-Bi nanosheet array: an efficient non-noble-metal bifunctional electrocatalyst toward full water splitting under near-neutral conditions[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(17):7806-7810. |
| APA | Ge, Ruixiang.,Du, Gu.,Asiri, Abdullah M..,Sun, Xuping.,Chen, Liang.,...&Hao, Shuai.(2017).In situ formation of a 3D core/shell structured Ni3N@Ni-Bi nanosheet array: an efficient non-noble-metal bifunctional electrocatalyst toward full water splitting under near-neutral conditions.JOURNAL OF MATERIALS CHEMISTRY A,5(17),7806-7810. |
| MLA | Ge, Ruixiang,et al."In situ formation of a 3D core/shell structured Ni3N@Ni-Bi nanosheet array: an efficient non-noble-metal bifunctional electrocatalyst toward full water splitting under near-neutral conditions".JOURNAL OF MATERIALS CHEMISTRY A 5.17(2017):7806-7810. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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