Influence of Enhanced O-2 Provision on the Discharge Performance of Li-air Batteries by Incorporating Fluoroether
文献类型：期刊论文
| 作者 | Wang, Deyu; Wan, Hao; Mao, Ya; Liu, Zixuan; Bai, Qingyou; Peng, Zhe; Bao, Jingjing; Wu, Gang; Liu, Yang; Xie, Jingying |
| 刊名 | CHEMSUSCHEM
 |
| 出版日期 | 2017 |
| 卷号 | 10期号:7页码:1385-1389 |
| ISSN号 | 1864-5631 |
| 英文摘要 | As the first step during discharge, the mass transfer of oxygen should play a crucial role in Li-air batteries to tailor the growth of discharge products, however, not enough attention has been paid to this issue. Herein, we introduce an oxygen-enriching cosolvent, 1,2-(1,1,2,2-tetrafluoroethoxy) ethane (FE1), into the electrolyte, and investigate its influence on the discharge performance. The incorporation of this novel cosolvent consistently enhances the oxygen solubility of the electrolyte, and improves the oxygen diffusivity following a volcano-shape trend peaking at 50% FE1. It is interesting that the discharge capacities obtained with the investigated electrolytes share the similar volcano trends as the oxygen transport under 50mAg(carbon)(-1) and higher current densities. The improved oxygen diffusion could benefit the volumetric utilization of the air cathode, especially at the separator side, probably owing to the fast oxygen transport to moderate its concentration gradient. Our results demonstrate the importance of oxygen provision, which easily becomes the capacity-determining factor. |
| 公开日期 | 2017-12-25 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/13890]  |
| 专题 | 2017专题 |
| 推荐引用方式 GB/T 7714 | Wang, Deyu,Wan, Hao,Mao, Ya,et al. Influence of Enhanced O-2 Provision on the Discharge Performance of Li-air Batteries by Incorporating Fluoroether[J]. CHEMSUSCHEM,2017,10(7):1385-1389. |
| APA | Wang, Deyu.,Wan, Hao.,Mao, Ya.,Liu, Zixuan.,Bai, Qingyou.,...&Xie, Jingying.(2017).Influence of Enhanced O-2 Provision on the Discharge Performance of Li-air Batteries by Incorporating Fluoroether.CHEMSUSCHEM,10(7),1385-1389. |
| MLA | Wang, Deyu,et al."Influence of Enhanced O-2 Provision on the Discharge Performance of Li-air Batteries by Incorporating Fluoroether".CHEMSUSCHEM 10.7(2017):1385-1389. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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