Anneal-induced transformation of phase structure, morphology and luminescence of GdPO4:Sm3+ nanomaterials synthesized by a hydrothermal method
文献类型：期刊论文
| 作者 | Xu, Chenggang; Zou, Xiao; He, Lihua; Tan, Dihao; Lei, Fengying; Jiang, Na; Zheng, Qiaoji; Lin, Dunmin; Liu, Yongfu |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2017 |
| 卷号 | 46期号:9页码:2948-2956 |
| ISSN号 | 1477-9226 |
| 英文摘要 | GdPO4 center dot H2O:xSm(3+) nanomaterials were synthesized via a facile hydrothermal method and the effects of Sm3+ concentrations and annealing temperature on the crystal structures, morphologies, and luminescent properties were studied. Doping of Sm3+ exhibited no obvious influence on the crystal structure for the non-annealed samples, which possessed a hexagonal structure and a nanorod shape. Under 401 nm excitation, GdPO4 center dot H2O:xSm(3+) displays a typical emission band with several peaks at 560, 596, and 640 nm. For the optimal sample of GdPO4 center dot H2O:1.75%Sm3+, as the annealing temperature was increased from 300 to 800 degrees C, the compound transformed from GdPO4 center dot H2O with a hexagonal symmetry to anhydrous GdPO4 with a monoclinic symmetry, and the morphologies varied from nanorods to ellipse-like shapes. The length of the nanorods was about 200 nm, whereas the ellipse-like shape exhibited a length of 100 nm and a diameter of 50 nm. The luminescent intensity was enhanced with the increased annealing temperature because the compound transformed from GdPO4 center dot H2O to anhydrous GdPO4 and the non-radiative transition was reduced due to variation in the morphology. Moreover, GdPO4 center dot H2O:1.75%Sm3+ exhibits paramagnetic performance. In addition, the potential applications in bioimaging and MRI were investigated. |
| 公开日期 | 2017-12-25 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/13944]  |
| 专题 | 2017专题 |
| 推荐引用方式 GB/T 7714 | Xu, Chenggang,Zou, Xiao,He, Lihua,et al. Anneal-induced transformation of phase structure, morphology and luminescence of GdPO4:Sm3+ nanomaterials synthesized by a hydrothermal method[J]. DALTON TRANSACTIONS,2017,46(9):2948-2956. |
| APA | Xu, Chenggang.,Zou, Xiao.,He, Lihua.,Tan, Dihao.,Lei, Fengying.,...&Liu, Yongfu.(2017).Anneal-induced transformation of phase structure, morphology and luminescence of GdPO4:Sm3+ nanomaterials synthesized by a hydrothermal method.DALTON TRANSACTIONS,46(9),2948-2956. |
| MLA | Xu, Chenggang,et al."Anneal-induced transformation of phase structure, morphology and luminescence of GdPO4:Sm3+ nanomaterials synthesized by a hydrothermal method".DALTON TRANSACTIONS 46.9(2017):2948-2956. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。