Kinetic characteristics up to 4.8 V of layered LiNi1/3Co1/3Mn1/3O2 cathode materials for high voltage lithium-ion batteries
文献类型：期刊论文
| 作者 | Zhang, Zhifeng; Zhang, Qinggang; Li, Jun; Li, Yantu; Zhang, Xianhui; Chen, Zhenlian; Schwarz, Bjoern; Sigel, Florian; Ehrenberg, Helmut; An, Ke |
| 刊名 | ELECTROCHIMICA ACTA
 |
| 出版日期 | 2017 |
| 卷号 | 227页码:152-161 |
| ISSN号 | 0013-4686 |
| 英文摘要 | Understanding the structure properties in deep delithiated states and electrochemical kinetics in the high potential window of LiNi1/3Co1/3Mn1/3O2 (NCM) cathode materials is essential to advance their performance in rechargeable lithium-ion batteries for 5 V chemistry. Here we report a layered single-phase NCM showing great structural reversibility and without H3 phase formation when charged up to 4.8 V at least for 5 cycles. However, the poor cluster scale conductivity results in inactive material in thick electrode during cycling, approximately 10% (w/w), may corresponding to the reduced capacity respective to thin electrode. The Co3+/Co4+ redox peaks are found clear and stable for cycles, lying between 4.5 similar to 5.0 V. That is tightly correlated to the fast Li-ion kinetic, i.e., the electrochemical behaviour of the NCM material is not limited by Li+ diffusion but behaving like in a thin layer. That is very different from previously reports on charge transfer mechanisms of cathode materials for lithium-ion batteries. (C) 2017 Elsevier Ltd. All rights reserved. |
| 公开日期 | 2017-12-25 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/13991]  |
| 专题 | 2017专题 |
| 推荐引用方式 GB/T 7714 | Zhang, Zhifeng,Zhang, Qinggang,Li, Jun,et al. Kinetic characteristics up to 4.8 V of layered LiNi1/3Co1/3Mn1/3O2 cathode materials for high voltage lithium-ion batteries[J]. ELECTROCHIMICA ACTA,2017,227:152-161. |
| APA | Zhang, Zhifeng.,Zhang, Qinggang.,Li, Jun.,Li, Yantu.,Zhang, Xianhui.,...&An, Ke.(2017).Kinetic characteristics up to 4.8 V of layered LiNi1/3Co1/3Mn1/3O2 cathode materials for high voltage lithium-ion batteries.ELECTROCHIMICA ACTA,227,152-161. |
| MLA | Zhang, Zhifeng,et al."Kinetic characteristics up to 4.8 V of layered LiNi1/3Co1/3Mn1/3O2 cathode materials for high voltage lithium-ion batteries".ELECTROCHIMICA ACTA 227(2017):152-161. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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