Mn Doping of CoP Nanosheets Array: An Efficient Electrocatalyst for Hydrogen Evolution Reaction with Enhanced Activity at All pH Values
文献类型：期刊论文
| 作者 | Liu, Tingting; Ma, Xiao; Liu, Danni; Hao, Shuai; Du, Gu; Ma, Yongjun; Asiri, Abdullah M.; Sun, Xuping; Chen, Liang |
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2017 |
| 卷号 | 7期号:1页码:98-102 |
| ISSN号 | 2155-5435 |
| 英文摘要 | Heteratom doping is a possible way to tune the hydrogen evolution reaction (HER) catalytic capability of electrocatalysts. In this work, we report the development of Mndoped CoP (Mn-Co-P) nanosheets array on Ti mesh (Mn-Co-P/Ti) as an efficient 3D HER electrocatalyst with good stability at all pH values. Electrochemical tests demonstrate that Mn doping leads to enhanced catalytic activity of CoP. In 0.5 M H2SO4, this Mn-Co-P/Ti catalyst drives 10 mA cm-2 at an overpotential of 49 mV, which is 32 mV less than that for CoP/Ti. To achieve the same current density, it demands overpotentials of 76 and 86 mV in 1.0 M KOH and phosphate-buffered saline, respectively. The enhanced HER activity for Mn-Co-P can be attributed to its more thermo-neutral hydrogen adsorption free energy than CoP, which is supported by density functional theory calculations. |
| 公开日期 | 2017-12-25 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/14117]  |
| 专题 | 2017专题 |
| 推荐引用方式 GB/T 7714 | Liu, Tingting,Ma, Xiao,Liu, Danni,et al. Mn Doping of CoP Nanosheets Array: An Efficient Electrocatalyst for Hydrogen Evolution Reaction with Enhanced Activity at All pH Values[J]. ACS CATALYSIS,2017,7(1):98-102. |
| APA | Liu, Tingting.,Ma, Xiao.,Liu, Danni.,Hao, Shuai.,Du, Gu.,...&Chen, Liang.(2017).Mn Doping of CoP Nanosheets Array: An Efficient Electrocatalyst for Hydrogen Evolution Reaction with Enhanced Activity at All pH Values.ACS CATALYSIS,7(1),98-102. |
| MLA | Liu, Tingting,et al."Mn Doping of CoP Nanosheets Array: An Efficient Electrocatalyst for Hydrogen Evolution Reaction with Enhanced Activity at All pH Values".ACS CATALYSIS 7.1(2017):98-102. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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