Clustered-Microcapsule-Shaped Microporous Carbon-Coated Sulfur Composite Synthesized via in Situ Oxidation
文献类型：期刊论文
| 作者 | Li, Chao; Wang, Qian; Liu, Honghong; Li, Rongrong; Yang, Minghui; Wang, Zhen-Bo; Zhang, Limei; Gu, Da-Ming |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2017 |
| 卷号 | 9期号:51页码:44512-44518 |
| 关键词 | Li-s Batteries Lithium-ion Batteries High-performance Hollow Carbon Metal-oxide Polysulfide Mediator Spheres Shell Nanocages Cathodes |
| 英文摘要 | Hollow materials as sulfur hosts have been intensively investigated to address the poor cycling stabilities of Li-S batteries. Herein, we report an enhanced hollow framework to improve the applicability of the sulfur confinement. A clustered-microcapsule-shaped microporous carbon coated sulfur (CM-S@MPC) composite is prepared from the clustered zinc sulfide precursor, through an in situ oxidation process. The high specific surface area and the in situ preparation guarantee the uniform distribution of sulfur inside the carbon microcapsule, even under a higher sulfur content of 83 wt %. In addition, the interconnected frame constructed by the stacking of carbon microcapsules also mitigates the lithium polysulfide loss by setting interlayered hurdles on their pathway along the outward diffusion. Hence, these enable a full demonstration of excellent cycling stability, compared to the control sample obtained via physical sulfur infiltration. The outstanding decay rate of 0.039% per cycle is achieved during 700 cycles at 1 C, even under high sulfur loading. |
| 学科主题 | Polymer Science |
| 语种 | 英语 |
| 公开日期 | 2018-12-04 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/17481]  |
| 专题 | 2017专题 |
| 推荐引用方式 GB/T 7714 | Li, Chao,Wang, Qian,Liu, Honghong,et al. Clustered-Microcapsule-Shaped Microporous Carbon-Coated Sulfur Composite Synthesized via in Situ Oxidation[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(51):44512-44518. |
| APA | Li, Chao.,Wang, Qian.,Liu, Honghong.,Li, Rongrong.,Yang, Minghui.,...&Gu, Da-Ming.(2017).Clustered-Microcapsule-Shaped Microporous Carbon-Coated Sulfur Composite Synthesized via in Situ Oxidation.ACS APPLIED MATERIALS & INTERFACES,9(51),44512-44518. |
| MLA | Li, Chao,et al."Clustered-Microcapsule-Shaped Microporous Carbon-Coated Sulfur Composite Synthesized via in Situ Oxidation".ACS APPLIED MATERIALS & INTERFACES 9.51(2017):44512-44518. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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