Synthesis of copolyesters with bio-based lauric diacid: structure and physico-mechanical studies
文献类型：期刊论文
| 作者 | Saada, Nesren A. H.; Na, Haining; Zhu, Jin; Chen, Meiling; Liu, Fei |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2017 |
| 卷号 | 7期号:87页码:55418-55426 |
| 关键词 | Dicarboxylic-acids Thermal-properties Thermomechanical Properties Polyester Elastomers Dodecanedioic Acid Chemical-structure Random Copolymers Polymers Polyethylene Behavior |
| 英文摘要 | Lauric diacid (LCDA), also known as 1,12-dodecanedioic acid, is used to develop a series of copolyesters along with 1,4-cyclohexanedicarboxylic acid (CHDA) and 1,4-butanediol (BDO). The resulting poly(butylene lauric dicarboxylate-co-butylene 1,4-cyclohexanedicarboxylate) (PBLC) is proved to be a random copolyester with three triad sequences. When the LCDA content increases from 20 to 60 mol%, T-m of the copolyester decreases from 133 to 57 degrees C. At the same time, the tensile modulus and strength decrease from 94 and 14 MPa to 40 and 5 MPa, respectively. Moreover, the elongation at break also drops from 640 to only 50%. However, further increasing the LCDA content to 80 mol%, the copolyester becomes amorphous with no Tm, and its tensile modulus, strength, and the elongation at break all improve significantly to 68 and 7 MPa, and over 1400%, respectively. More importantly, for the homo-polymer poly(butylene lauric dicarboxylate) (PBL), it has a relatively high T-m of 73 degrees C compared to that of polycaprolactone (PCL), but lower tensile modulus and strength, and significantly higher ductility, compared to those of PCL, linear low density polyethylene, and polybutylene succinate. |
| 学科主题 | Materials Science ; Physics |
| 语种 | 英语 |
| 公开日期 | 2018-12-04 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/17510]  |
| 专题 | 2017专题 |
| 推荐引用方式 GB/T 7714 | Saada, Nesren A. H.,Na, Haining,Zhu, Jin,et al. Synthesis of copolyesters with bio-based lauric diacid: structure and physico-mechanical studies[J]. RSC ADVANCES,2017,7(87):55418-55426. |
| APA | Saada, Nesren A. H.,Na, Haining,Zhu, Jin,Chen, Meiling,&Liu, Fei.(2017).Synthesis of copolyesters with bio-based lauric diacid: structure and physico-mechanical studies.RSC ADVANCES,7(87),55418-55426. |
| MLA | Saada, Nesren A. H.,et al."Synthesis of copolyesters with bio-based lauric diacid: structure and physico-mechanical studies".RSC ADVANCES 7.87(2017):55418-55426. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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