Synthesis of Eugenol-Based Silicon-Containing Benzoxazines and Their Applications as Bio-Based Organic Coatings
文献类型：期刊论文
| 作者 | Dai, Jinyue; Yang, Shimin; Teng, Na; Liu, Yuan; Liu, Xiaoqing; Zhu, Jin; Zhao, Jun |
| 刊名 | COATINGS
 |
| 出版日期 | 2018 |
| 卷号 | 8期号:3 |
| 关键词 | Main-chain Polymers Polybenzoxazine Resin Cardanol Thermosets Oligomers Networks Guaiacol Furan |
| 英文摘要 | In this work, several bio-based main-chain type benzoxazine oligomers (MCBO) were synthesized from eugenol derivatives via polycondensation reaction with paraformaldehyde and different diamine. Afterwards, their chemical structures were confirmed by Fourier Transform Infrared Spectroscopy (FT-IR) and Nuclear Magnetic Resonance Spectroscopy (H-1-NMR). The curing reaction was monitored by Differential Scanning Calorimetry (DSC) and FT-IR. The polybenzoxazine films were prepared via thermal ring-opening reaction of benzoxazine groups without solvent, and their thermodynamic properties, thermal stability, and coating properties were investigated in detail. Results indicated that the cured films exhibited good thermal stability and mechanical properties, showing 10% thermal weight loss (T-d10%) temperature as high as 408 degrees C and modulus at a room temperature of 2100 MPa as well as the glass transition temperature of 123 degrees C. In addition, the related coatings exhibited high hardness, excellent adhesion, good flexibility, low moisture absorption, and outstanding solvent resistance. |
| 学科主题 | Materials Science |
| 语种 | 英语 |
| 公开日期 | 2018-12-04 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/16767]  |
| 专题 | 2018专题 |
| 推荐引用方式 GB/T 7714 | Dai, Jinyue,Yang, Shimin,Teng, Na,et al. Synthesis of Eugenol-Based Silicon-Containing Benzoxazines and Their Applications as Bio-Based Organic Coatings[J]. COATINGS,2018,8(3). |
| APA | Dai, Jinyue.,Yang, Shimin.,Teng, Na.,Liu, Yuan.,Liu, Xiaoqing.,...&Zhao, Jun.(2018).Synthesis of Eugenol-Based Silicon-Containing Benzoxazines and Their Applications as Bio-Based Organic Coatings.COATINGS,8(3). |
| MLA | Dai, Jinyue,et al."Synthesis of Eugenol-Based Silicon-Containing Benzoxazines and Their Applications as Bio-Based Organic Coatings".COATINGS 8.3(2018). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。