Catalytic PVDF membrane for continuous reduction and separation of p-nitrophenol and methylene blue in emulsified oil solution
文献类型:期刊论文
作者 | Wu, Ziyang; Liu, Fu; Ye, Jianrong; Shen, Liqiang; She, Zhen; Li, Tiantian; Wang, Jianqiang |
刊名 | CHEMICAL ENGINEERING JOURNAL
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出版日期 | 2018 |
卷号 | 334页码:579-586 |
关键词 | Ultrafiltration Membrane Oil/water Separation Composite Membranes Degradation Polydopamine Nanoparticle Reverse Peroxymonosulfate 4-nitrophenol Performance |
英文摘要 | Removal of aromatic contaminants from water has been a challenge in the field of environmental remediation. In order to remove these contaminants efficiently, we developed a catalytic finger reactor based on PVDF membrane for continuous reduction of p-nitrophenol (4-NP) and methylene blue (MB) in chloroform-in-water emulsion by integration of physical sieving and chemical reaction. The catalytic finger reactor was elaborately constructed via the assembly of Au nanoparticles (AuNPs) inside the finger-like pores in PVDF membrane through a dynamic flow strategy by taking advantage of the pre-coated polydopamine layer. The wettability, morphological and distribution of AuNPs in the finger-like pores were revealed by contact angle, SEM and EDX. The prepared catalytic finger reactor reduced> 99% of 4-NP (2.72x10(-4) M) and MB (5.35x10(-4) M) at a flow rate of 0.015 mL/cm(2)s, corresponding to a residence time of 1.12 s and a linear velocity of 0.021 cm/s. Moreover, the catalytic PVDF membrane showed great reduction of 4-NP and high rejection to chloroform-in-water emulsion simultaneously in the continuous filtration process. Overall, the catalytic finger reactor realized the spontaneous and continuous reduction of 4-NP and MB in a flowing mode and as well as the emulsion separation. |
学科主题 | Engineering ; Polymer Science |
语种 | 英语 |
公开日期 | 2018-12-04 |
源URL | [http://ir.nimte.ac.cn/handle/174433/16810] ![]() |
专题 | 2018专题 |
推荐引用方式 GB/T 7714 | Wu, Ziyang,Liu, Fu,Ye, Jianrong,et al. Catalytic PVDF membrane for continuous reduction and separation of p-nitrophenol and methylene blue in emulsified oil solution[J]. CHEMICAL ENGINEERING JOURNAL,2018,334:579-586. |
APA | Wu, Ziyang.,Liu, Fu.,Ye, Jianrong.,Shen, Liqiang.,She, Zhen.,...&Wang, Jianqiang.(2018).Catalytic PVDF membrane for continuous reduction and separation of p-nitrophenol and methylene blue in emulsified oil solution.CHEMICAL ENGINEERING JOURNAL,334,579-586. |
MLA | Wu, Ziyang,et al."Catalytic PVDF membrane for continuous reduction and separation of p-nitrophenol and methylene blue in emulsified oil solution".CHEMICAL ENGINEERING JOURNAL 334(2018):579-586. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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