Critical pore dimensions for gases in a BTESE-derived organic-inorganic hybrid silica: A theoretical analysis
文献类型：期刊论文
| 作者 | Ji, Guozhao; Chen, Liang; Gao, Xuechao; Wang, Jiacheng; Peng, Li; Gu, Xuehong |
| 刊名 | SEPARATION AND PURIFICATION TECHNOLOGY
 |
| 出版日期 | 2018 |
| 卷号 | 191页码:27-37 |
| 关键词 | Organosilica Membranes Nanoporous Materials Diffusion Mechanism Carbon Nanotubes Transport Permeation Model Simulation Separation Zeolites |
| 英文摘要 | This work studied the critical pore dimensions for different light gases in disordered microporous hybrid silica which was derived from 1,2-bis(triethoxysilyl)ethane (BTESE) precursor. The Lennard-Jones (LJ) parameters of the material, obtained from high pressure isotherms of light gases, were employed to evaluate dispersive interaction, diffusivity and adsorption coefficient in the nanopores of the hybrid silica, and the results demonstrated that the entrance barrier was the key factor to break down the separation limits confining the Graham law and the Knudsen model by gas kinetic theory. Finally, the critical pore dimensions for different resistance dominated regions were evaluated, which theoretically explained why the separation capacity of the hybrid silica was less promising than pure silica for the purpose of gas separation. |
| 学科主题 | Chemistry ; Electrochemistry ; Instruments & Instrumentation |
| 语种 | 英语 |
| 公开日期 | 2018-12-04 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/16855]  |
| 专题 | 2018专题 |
| 推荐引用方式 GB/T 7714 | Ji, Guozhao,Chen, Liang,Gao, Xuechao,et al. Critical pore dimensions for gases in a BTESE-derived organic-inorganic hybrid silica: A theoretical analysis[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2018,191:27-37. |
| APA | Ji, Guozhao,Chen, Liang,Gao, Xuechao,Wang, Jiacheng,Peng, Li,&Gu, Xuehong.(2018).Critical pore dimensions for gases in a BTESE-derived organic-inorganic hybrid silica: A theoretical analysis.SEPARATION AND PURIFICATION TECHNOLOGY,191,27-37. |
| MLA | Ji, Guozhao,et al."Critical pore dimensions for gases in a BTESE-derived organic-inorganic hybrid silica: A theoretical analysis".SEPARATION AND PURIFICATION TECHNOLOGY 191(2018):27-37. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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