Highly soluble phenylethynyl terminated oligoimides derived from 5(6)-amino-1-(4-aminophenyl)-1,3,3-trimethylindane, 4,4 '-oxydianiline and mixed thioetherdiphthalic anhydride isomers
文献类型：期刊论文
| 作者 | Liu, Yinfeng; Li, Hanyuan; Wang, Wei; Chen, Guofei; Fang, Xingzhong |
| 刊名 | JOURNAL OF POLYMER RESEARCH
 |
| 出版日期 | 2018 |
| 卷号 | 25期号:1 |
| 关键词 | Imide Oligomers Aromatic Polyimides 2 Adhesive Properties 3 Composites 3' Temperature 4'-biphenyltetracarboxylic Dianhydride Resins Stability Peti-298 Matrix |
| 英文摘要 | Novel highly soluble phenylethynyl-endcapped oligoimides derived from mixed thioetherdiphthalic anhydride isomers (m-TDPA) and 5(6)-amino-1-(4-aminophenyl)-1,3,3-trimethylindane (DAPI), 4,4'-oxydianiline (4,4'-ODA) with 4phenylethynylphthalic anhydride (PEPA) as a reactive endcapping agent were synthesized. The calculated molecular weights of all the oligoimides were 2500 g.mol(-1). The effect of the mole ratio of DAPI/4,4'-ODA on solubility and melt viscosity of oligoimides as well as the thermal and mechanical properties of cured polyimide films was investigated. Experimental results indicated that DAPI greatly improved the solubility (>30 wt.%) of the oligoimides in low boiling points solvents when the content ofDAPI was more than 10 mol% per total diamine. All the oligoimides exhibited very good processabilitywith minimum melt viscosity lower than 60 Pa.s at about 330 degrees C. Tough and brown films were obtained after thermally cured at 370 degrees C for 1 h and dynamic mechanical analysis (DMA) showed that glass transition temperatures of the cured films increased up to 340 degrees C with the increasing content of DAPI. However, the thermal stability and mechanical properties decreased with the increase of DAPI content. The temperature of 5% weight loss was higher than 470 degrees C in both air and N-2 atmosphere obtained by thermogravimetric analysis (TGA). And the tensile strengths of the cured films were about 60 MPa. |
| 学科主题 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| 公开日期 | 2018-12-04 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/16884]  |
| 专题 | 2018专题 |
| 推荐引用方式 GB/T 7714 | Liu, Yinfeng,Li, Hanyuan,Wang, Wei,et al. Highly soluble phenylethynyl terminated oligoimides derived from 5(6)-amino-1-(4-aminophenyl)-1,3,3-trimethylindane, 4,4 '-oxydianiline and mixed thioetherdiphthalic anhydride isomers[J]. JOURNAL OF POLYMER RESEARCH,2018,25(1). |
| APA | Liu, Yinfeng,Li, Hanyuan,Wang, Wei,Chen, Guofei,&Fang, Xingzhong.(2018).Highly soluble phenylethynyl terminated oligoimides derived from 5(6)-amino-1-(4-aminophenyl)-1,3,3-trimethylindane, 4,4 '-oxydianiline and mixed thioetherdiphthalic anhydride isomers.JOURNAL OF POLYMER RESEARCH,25(1). |
| MLA | Liu, Yinfeng,et al."Highly soluble phenylethynyl terminated oligoimides derived from 5(6)-amino-1-(4-aminophenyl)-1,3,3-trimethylindane, 4,4 '-oxydianiline and mixed thioetherdiphthalic anhydride isomers".JOURNAL OF POLYMER RESEARCH 25.1(2018). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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