Facile preparation of epoxy based elastomers with tunable T(g)s and mechanical properties
文献类型:期刊论文
作者 | Dai, Zhendong; Chen, Bin; Li, Jingyu; Liu, Tong; Zhao, Haichao |
刊名 | RSC ADVANCES
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出版日期 | 2018 |
卷号 | 8期号:24页码:13474-13481 |
关键词 | Shape-memory Polymers Cationic Copolymerization Resins Degradation Resistance Behaviors Dgeba |
英文摘要 | In this work, a secondary amine-capped polyaspartic ester (PAE-D230) was synthesized using diethyl maleate and amine-terminated polyether (D230) via Michael addition reaction. By modulating the molar ratio of preliminary amine containing D230 and secondary amine-capped PAE-D230 during the curing process with epoxy precursor E44, we obtained epoxy shape memory polymers with tunable T(g)s(-12-20 degrees C), controllable mechanical properties with tensile stress from 0.8 to 14.1 MPa, tensile modulus from 0.7 to 872.0 MPa, and elongation at break from 45.2 to 195.1%. The influence of the composition of curing components on the thermal properties, thermomechanical, mechanical properties, shape memory effect were systematically studied by DSC, TGA, DMA, tensile-stress measurements. |
学科主题 | Chemistry ; Engineering |
语种 | 英语 |
公开日期 | 2018-12-04 |
源URL | [http://ir.nimte.ac.cn/handle/174433/16912] ![]() |
专题 | 2018专题 |
推荐引用方式 GB/T 7714 | Dai, Zhendong,Chen, Bin,Li, Jingyu,et al. Facile preparation of epoxy based elastomers with tunable T(g)s and mechanical properties[J]. RSC ADVANCES,2018,8(24):13474-13481. |
APA | Dai, Zhendong,Chen, Bin,Li, Jingyu,Liu, Tong,&Zhao, Haichao.(2018).Facile preparation of epoxy based elastomers with tunable T(g)s and mechanical properties.RSC ADVANCES,8(24),13474-13481. |
MLA | Dai, Zhendong,et al."Facile preparation of epoxy based elastomers with tunable T(g)s and mechanical properties".RSC ADVANCES 8.24(2018):13474-13481. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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