Metal-Organic Framework Anchored with a Lewis Pair as a New Paradigm for Catalysis
文献类型：期刊论文
| 作者 | Niu, Zheng; Cheng, Yuchuan; Ma, Jian-Gong; Aguila, Briana; Ma, Shengqian; Perman, Jason; Lan, Pui Ching; Sun, Qi; Gunatilleke, Wilarachchige D. C. Bhagya |
| 刊名 | CHEM
 |
| 出版日期 | 2018 |
| 卷号 | 4期号:11页码:2587-2599 |
| 关键词 | Acid-base Pairs Hydrogenation Reactions Oxygen Evolution Co2 Encapsulation Conversion Alkenes Transformations Polymerization Hydroboration |
| 英文摘要 | Lewis pair (LP) chemistry has shown broad applications in the catalysis field. However, one significant challenge has been recognized as the instability for most homogeneous LP catalysts upon recycling, thus inevitably leading to dramatic loss in catalytic activity. Additionally, current heterogeneous LP catalysts suffer from low surface area, which largely limits their catalytic efficiency, thereby restricting their potential applications. In this work, we report the successful introduction of LPs, classical and frustrated, into a metal-organic framework (MOF) that features high surface and ordered pore structure via a stepwise anchoring strategy. Not only can the LP be stabilized by the strong coordination interaction between the LP and MOF, but the resultant MOF-LP also demonstrates excellent catalysis performance with interesting size and steric selectivity. Given the broad applicability of LPs, our work therefore paves a way for advancing MOF-LP as a new paradigm for catalysis. |
| 学科主题 | Chemistry ; Materials Science |
| 语种 | 英语 |
| 公开日期 | 2018-12-04 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/17031]  |
| 专题 | 2018专题 |
| 推荐引用方式 GB/T 7714 | Niu, Zheng,Cheng, Yuchuan,Ma, Jian-Gong,et al. Metal-Organic Framework Anchored with a Lewis Pair as a New Paradigm for Catalysis[J]. CHEM,2018,4(11):2587-2599. |
| APA | Niu, Zheng.,Cheng, Yuchuan.,Ma, Jian-Gong.,Aguila, Briana.,Ma, Shengqian.,...&Gunatilleke, Wilarachchige D. C. Bhagya.(2018).Metal-Organic Framework Anchored with a Lewis Pair as a New Paradigm for Catalysis.CHEM,4(11),2587-2599. |
| MLA | Niu, Zheng,et al."Metal-Organic Framework Anchored with a Lewis Pair as a New Paradigm for Catalysis".CHEM 4.11(2018):2587-2599. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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