Polymerization driven monomer passage through monolayer chemical vapour deposition graphene
文献类型：期刊论文
| 作者 | Liao, Zhongquan; Jordan, Rainer; Cuniberti, Gianaurelio; Zschech, Ehrenfried; Chen, Tao; Gutierrez, Rafael; Amin, Ihsan; Xiao, Peng; Liu, Xiaoling; Dianat, Arezoo |
| 刊名 | NATURE COMMUNICATIONS
 |
| 出版日期 | 2018 |
| 卷号 | 9 |
| 关键词 | Single-layer Graphene Radical Polymerization Raman-spectroscopy Intrinsic Defects Porous Graphene Permeation Transport Membranes Brushes Chemistry |
| 英文摘要 | Mass transport through graphene is receiving increasing attention due to the potential for molecular sieving. Experimental studies are mostly limited to the translocation of protons, ions, and water molecules, and results for larger molecules through graphene are rare. Here, we perform controlled radical polymerization with surface-anchored self-assembled initiator monolayer in a monomer solution with single-layer graphene separating the initiator from the monomer. We demonstrate that neutral monomers are able to pass through the graphene (via native defects) and increase the graphene defects ratio (Raman I-D/I-G) from ca. 0.09 to 0.22. The translocations of anionic and cationic monomers through graphene are significantly slower due to chemical interactions of monomers with the graphene defects. Interestingly, if micropatterned initiator-monolayers are used, the translocations of anionic monomers apparently cut the graphene sheet into congruent microscopic structures. The varied interactions between monomers and graphene defects are further investigated by quantum molecular dynamics simulations. |
| 学科主题 | Materials Science ; Physics |
| 语种 | 英语 |
| 公开日期 | 2018-12-04 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/17138]  |
| 专题 | 2018专题 |
| 推荐引用方式 GB/T 7714 | Liao, Zhongquan,Jordan, Rainer,Cuniberti, Gianaurelio,et al. Polymerization driven monomer passage through monolayer chemical vapour deposition graphene[J]. NATURE COMMUNICATIONS,2018,9. |
| APA | Liao, Zhongquan.,Jordan, Rainer.,Cuniberti, Gianaurelio.,Zschech, Ehrenfried.,Chen, Tao.,...&Zhang, Tao.(2018).Polymerization driven monomer passage through monolayer chemical vapour deposition graphene.NATURE COMMUNICATIONS,9. |
| MLA | Liao, Zhongquan,et al."Polymerization driven monomer passage through monolayer chemical vapour deposition graphene".NATURE COMMUNICATIONS 9(2018). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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