Water oxidation by a manganese-potassium cluster: Mn oxide as a kinetically dominant "true" catalyst for water oxidation
文献类型：期刊论文
| 作者 | Bikas, Rahman; Bagheri, Robabeh; Song, Zhenlun; Chernev, Petko; Lis, Tadeusz; Dau, Holger; Mohammadi, Mohammad Reza; Mousazade, Younes; Najafpour, Mohammad Mahdi |
| 刊名 | CATALYSIS SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2018 |
| 卷号 | 8期号:17页码:4390-4398 |
| 关键词 | Oxygen-evolving Center Cerium(Iv) Ammonium-nitrate Photosystem-ii Photosynthesis Complex Evolution Photolysis Chemistry Precursor Insights |
| 英文摘要 | Nature uses an Mn cluster for water oxidation, and thus, water oxidation using Mn clusters is interesting when used in artificial water-splitting systems. An important question is whether an Mn cluster is a true catalyst for water oxidation or not. Herein, an Mn-K cluster was investigated for electrochemical water oxidation to find the true and the kinetically dominant catalyst using X-ray absorption spectroscopy, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, and electrochemical methods. The experiments showed that conversion into nanosized Mn oxide occurred for the cluster, and the nanosized Mn oxides are the true catalyst for water oxidation. |
| 学科主题 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| 公开日期 | 2018-12-04 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/17207]  |
| 专题 | 2018专题 |
| 推荐引用方式 GB/T 7714 | Bikas, Rahman,Bagheri, Robabeh,Song, Zhenlun,et al. Water oxidation by a manganese-potassium cluster: Mn oxide as a kinetically dominant "true" catalyst for water oxidation[J]. CATALYSIS SCIENCE & TECHNOLOGY,2018,8(17):4390-4398. |
| APA | Bikas, Rahman.,Bagheri, Robabeh.,Song, Zhenlun.,Chernev, Petko.,Lis, Tadeusz.,...&Najafpour, Mohammad Mahdi.(2018).Water oxidation by a manganese-potassium cluster: Mn oxide as a kinetically dominant "true" catalyst for water oxidation.CATALYSIS SCIENCE & TECHNOLOGY,8(17),4390-4398. |
| MLA | Bikas, Rahman,et al."Water oxidation by a manganese-potassium cluster: Mn oxide as a kinetically dominant "true" catalyst for water oxidation".CATALYSIS SCIENCE & TECHNOLOGY 8.17(2018):4390-4398. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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