Improvement of furanic diether selectivity by adjusting Bronsted and Lewis acidity
文献类型：期刊论文
| 作者 | He, Yulian; Zhang, Yajie; Wang, Lei; Ma, Zhongsen; Dong, Ping; Hu, Hualei; Fang, Wenting |
| 刊名 | APPLIED CATALYSIS A-GENERAL
 |
| 出版日期 | 2018 |
| 卷号 | 565页码:146-151 |
| 关键词 | Reductive Etherification Furfuryl Alcohol Transfer Hydrogenation Biodiesel Components Benzene Alkylation Zsm-5 Catalyst Cetane Number Conversion Zeolites Ethanol |
| 英文摘要 | Furanic diethers are considered as one of potential biofuels or green solvents. 2,5-Bis(methoxymethyl)furan (BMMF), diether of 2,5-bis(hydroxymethyl)furan (BHMF) with methanol, is difficult to effectively synthesize in traditional homogeneous catalytic systems due to active groups of BHMF. In this case, HCl and AlCl3, representatives of Bronsted and Lewis acid, are separately employed to explore catalytic performance in BHMF etherification. We also demonstrated that Lewis and Bronsted acid not only synergistically catalyze the etherification but also take respectively charge of main and side reactions. Subsequently, the catalytic performance of ZSM-5 and modified ZSM-5 proved this conclusion. High yield and selectivity of BMMF catalyzed by 1.5%Sn-ZSM-5 was obtained, about 95%, which may be attributed to suitable Bronsted and Lewis acidity as well as pore structure. This suggests that synthesis of BMMF by using solid acid is possible in the future industrialization. |
| 学科主题 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| 公开日期 | 2018-12-04 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/17211]  |
| 专题 | 2018专题 |
| 推荐引用方式 GB/T 7714 | He, Yulian,Zhang, Yajie,Wang, Lei,et al. Improvement of furanic diether selectivity by adjusting Bronsted and Lewis acidity[J]. APPLIED CATALYSIS A-GENERAL,2018,565:146-151. |
| APA | He, Yulian.,Zhang, Yajie.,Wang, Lei.,Ma, Zhongsen.,Dong, Ping.,...&Fang, Wenting.(2018).Improvement of furanic diether selectivity by adjusting Bronsted and Lewis acidity.APPLIED CATALYSIS A-GENERAL,565,146-151. |
| MLA | He, Yulian,et al."Improvement of furanic diether selectivity by adjusting Bronsted and Lewis acidity".APPLIED CATALYSIS A-GENERAL 565(2018):146-151. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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