High-Performance Electrohydrogenation of N-2 to NH3 Catalyzed by Multishelled Hollow Cr2O3 Microspheres under Ambient Conditions
文献类型：期刊论文
| 作者 | Chen, Liang; Xie, Fengyu; Cui, Guanwei; Tian, Ziqi; Luo, Yonglan; Ma, Yongjun; Qiu, Weibin; Zhang, Ya; Li, Tingshuai; Sun, Xuping |
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2018 |
| 卷号 | 8期号:9页码:8540-8544 |
| 关键词 | Atmospheric-pressure Electrochemical Synthesis Nitrogen Reduction Ammonia-synthesis Oxygen Vacancies Low-temperature Visible-light Dinitrogen Conversion Nanosheets |
| 英文摘要 | Electrohydrogenation of N-2 to NH3 is emerging as an environmentally benign strategy to tackle the issues associated with the energy-intensive, CO2-emitting Haber-Bosch process. However, the method is severely challenged by N-2 activation and needs efficient N-2 reduction reaction (NRR) catalysts. Here, we report that multishelled hollow Cr2O3 microspheres (MHCMs), which are synthesized by a facile synthetic route, can serve as efficient and selective non-noble metal electrocatalysts for NRR. In 0.1 M Na2SO4 solution, the MHCMs achieve a high Faradaic efficiency (6.78%) and a large NH3 yield (25.3 mu g h(-1) mg(cat)(-1)) at -0.9 V vs reversible hydrogen electrode. The MHCMs also exhibit high stability during the reaction. Density functional theory calculations suggest that NRR over MHCMs occurs via both distal associative and partially alternative routes. |
| 学科主题 | Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| 公开日期 | 2018-12-04 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/17216]  |
| 专题 | 2018专题 |
| 推荐引用方式 GB/T 7714 | Chen, Liang,Xie, Fengyu,Cui, Guanwei,et al. High-Performance Electrohydrogenation of N-2 to NH3 Catalyzed by Multishelled Hollow Cr2O3 Microspheres under Ambient Conditions[J]. ACS CATALYSIS,2018,8(9):8540-8544. |
| APA | Chen, Liang.,Xie, Fengyu.,Cui, Guanwei.,Tian, Ziqi.,Luo, Yonglan.,...&Sun, Xuping.(2018).High-Performance Electrohydrogenation of N-2 to NH3 Catalyzed by Multishelled Hollow Cr2O3 Microspheres under Ambient Conditions.ACS CATALYSIS,8(9),8540-8544. |
| MLA | Chen, Liang,et al."High-Performance Electrohydrogenation of N-2 to NH3 Catalyzed by Multishelled Hollow Cr2O3 Microspheres under Ambient Conditions".ACS CATALYSIS 8.9(2018):8540-8544. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。