New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel
文献类型：期刊论文
| 作者 | Wang, Pu; Du, Shiyu; Huang, Qing; Shi, Weiqun; Yan, Yongde; Ji, Debin; Zhang, Yiming; Zhang, Milin |
| 刊名 | ELECTROCHEMISTRY COMMUNICATIONS
 |
| 出版日期 | 2018 |
| 卷号 | 93页码:180-182 |
| 关键词 | Molten-salt Electronegativity Electrodes Energy |
| 英文摘要 | In this work, the electrochemical behavior of lanthanides (except promethium) on several active cathodes in LiCl-KCl molten salts was investigated. We have discovered that the reduction potentials of lanthanide alloys present a "bimodal effect". A numerical model was established based on the result of multiple linear regression analyses, which indicates that the reduction potentials are correlated with differences in atomic radii and differences in electronegativity. Employing the fitted formulae, which provide a preliminary model of the behavior of these elements in electrolysis-based pyroprocessing, the electrochemistry of both lanthanides and actinides on active metal cathodes could be reasonably estimated. |
| 学科主题 | Polymer Science |
| 语种 | 英语 |
| 公开日期 | 2018-12-04 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/17284]  |
| 专题 | 2018专题 |
| 推荐引用方式 GB/T 7714 | Wang, Pu,Du, Shiyu,Huang, Qing,et al. New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel[J]. ELECTROCHEMISTRY COMMUNICATIONS,2018,93:180-182. |
| APA | Wang, Pu.,Du, Shiyu.,Huang, Qing.,Shi, Weiqun.,Yan, Yongde.,...&Zhang, Milin.(2018).New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel.ELECTROCHEMISTRY COMMUNICATIONS,93,180-182. |
| MLA | Wang, Pu,et al."New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel".ELECTROCHEMISTRY COMMUNICATIONS 93(2018):180-182. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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