Carboxylic ester-terminated fulleropyrrolidine as an efficient electron transport material for inverted perovskite solar cells
文献类型：期刊论文
| 作者 | Guo, Qiang; Chang, Junwei; Wang, Ying-Chiao; Song, Changjian; Zhu, Liping; Fang, Junfeng |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY C
 |
| 出版日期 | 2018 |
| 卷号 | 6期号:26页码:6982-6987 |
| 关键词 | Performance Layer Iodide Enhancement Ch3nh3pbi3 Polymer Crystallization Deposition Lengths Film |
| 英文摘要 | The interfacial contacts between perovskite crystals and metal electrodes play a significant role in efficient charge transfer in perovskite solar cells (PSCs). In this work, C-60 pyrrolidine tris-acid ethyl ester (CPTA-E) has been employed to form a uniform electron transport layer (ETL) covering the perovskite surface in p-i-n-structured PSCs to replace the traditional (6,6)-phenyl-C-61-butyric acid methyl ester (PCBM) ETL. X-ray photoelectron spectroscopy analysis of the perovskite/CPTA-E interface reveals that there are strong coordination interactions between the perovskite and CPTA-E, which are beneficial for the adhesion of the CPTA-E ETL on the perovskite surface. On the other hand, steady-state photoluminescence and time-resolved photoluminescence studies of the perovskite films with different quenching layers confirm that CPTA-E ETL has a preferable charge quenching effect compared to the PCBM ETL, which suggests that the CPTA-E ETL has a superior electron extraction and transport ability. The corresponding CPTA-E ETL-based device exhibits a champion power conversion efficiency (PCE) of 17.44% with less hysteresis. Moreover, the steady-state photocurrent output of the CPTA-E-containing PSC is prolonged compared to that of the PCBM-based device. Therefore, this work provides a viable strategy to design suitable electron transport materials for high-performance PSCs. |
| 学科主题 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| 公开日期 | 2018-12-04 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/17317]  |
| 专题 | 2018专题 |
| 推荐引用方式 GB/T 7714 | Guo, Qiang,Chang, Junwei,Wang, Ying-Chiao,et al. Carboxylic ester-terminated fulleropyrrolidine as an efficient electron transport material for inverted perovskite solar cells[J]. JOURNAL OF MATERIALS CHEMISTRY C,2018,6(26):6982-6987. |
| APA | Guo, Qiang,Chang, Junwei,Wang, Ying-Chiao,Song, Changjian,Zhu, Liping,&Fang, Junfeng.(2018).Carboxylic ester-terminated fulleropyrrolidine as an efficient electron transport material for inverted perovskite solar cells.JOURNAL OF MATERIALS CHEMISTRY C,6(26),6982-6987. |
| MLA | Guo, Qiang,et al."Carboxylic ester-terminated fulleropyrrolidine as an efficient electron transport material for inverted perovskite solar cells".JOURNAL OF MATERIALS CHEMISTRY C 6.26(2018):6982-6987. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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