Color-tunable Ca10Na(PO4)(7):Ce3+/Tb3+/Mn2+ phosphor via energy transfer
文献类型:期刊论文
作者 | Tian, Yue; Shi, Qiufeng; Cui, Cai'e; Wang, Lei; Liu, Yongfu; Huang, Ping; Sun, Jingru |
刊名 | JOURNAL OF RARE EARTHS
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出版日期 | 2018 |
卷号 | 36期号:6页码:567-574 |
关键词 | Light-emitting-diodes White-light Luminescence Properties Transfer Behavior W-leds Mn2++ Ce3++ Tb3++ Photoluminescence Emission |
英文摘要 | A series of Ca10Na(PO4)(7):Ce3+/Tb3+/Mn2+ (CNPO:Ce3+/Tb3+/Mn2+) phosphors with high brightness were synthesized by high-temperature solid-state method. X-ray diffraction (XRD), scanning electron microscopy (SEM), diffuse reflectance spectra (DRS), photoluminescence (PL) spectra, luminescence decay curves and thermally stability were performed to characterize the as-prepared samples. For Ce3+-doped samples, an intense and broad band emission is present under 265 nm excitation. When Ce3+ and Tb3+ are codoped, energy transfer (ET) process from Ce3+ to Tb3+ is demonstrated with electric dipole-dipole interaction. The internal and external quantum efficiencies (QEs) of CNPO:0.15Ce(3+), 0.04Tb(3+), 0.005Mn(2+) are measured to 76.79% and 54.11% under 265 nm excitation and temperature-dependent PL intensity can remain 51.78% at 150 degrees C of its initial intensity at 25 degrees C. It is indicated that single-phased white light-emitting CNPO:Ce3+/Tb3+/Mn2+ phosphor can serve as a promising phosphor for illumination devices. (C) 2018 Published by Elsevier B.V. |
学科主题 | Engineering ; Polymer Science |
语种 | 英语 |
公开日期 | 2018-12-04 |
源URL | [http://ir.nimte.ac.cn/handle/174433/17446] ![]() |
专题 | 2018专题 |
推荐引用方式 GB/T 7714 | Tian, Yue,Shi, Qiufeng,Cui, Cai'e,et al. Color-tunable Ca10Na(PO4)(7):Ce3+/Tb3+/Mn2+ phosphor via energy transfer[J]. JOURNAL OF RARE EARTHS,2018,36(6):567-574. |
APA | Tian, Yue.,Shi, Qiufeng.,Cui, Cai'e.,Wang, Lei.,Liu, Yongfu.,...&Sun, Jingru.(2018).Color-tunable Ca10Na(PO4)(7):Ce3+/Tb3+/Mn2+ phosphor via energy transfer.JOURNAL OF RARE EARTHS,36(6),567-574. |
MLA | Tian, Yue,et al."Color-tunable Ca10Na(PO4)(7):Ce3+/Tb3+/Mn2+ phosphor via energy transfer".JOURNAL OF RARE EARTHS 36.6(2018):567-574. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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