From Furan to High Quality Bio-based Poly(ethylene furandicarboxylate)
文献类型：期刊论文
| 作者 | Zhu, Jin; Liu, Xiao-Qing; Wang, Jing-Gang |
| 刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
 |
| 出版日期 | 2018 |
| 卷号 | 36期号:6页码:720-727 |
| 关键词 | 2 Catalytic Conversion 5-furandicarboxylic Acid Furan-2 Aerobic Oxidation 5-dicarboxylic Acid Carbon Biomass Hmf Polyester 2 Acylation 5-diformylfuran |
| 英文摘要 | 2,5-Furandicarboxylic acid (2,5-FDCA) has been regarded as the ideal bio-based alternative to terephthalic acid (TPA). In recent years, great efforts have been made to synthesize 2,5-FDCA through the following methods: (1) oxidation of 5-hydroxymethylfurfural (HMF) in the presence of complex biocatalyst or metallic catalyst; (2) conversion of 2-furoic acid via the well-known Henkel Reaction. Herein, a new strategy for the synthesis of 2,5-FDCA from furan and acetic anhydride under mild condition is reported. The purity of the resulted 2,5-FDCA was above 99.9%. Acetic acid and iodoform generated in the reaction were recyclable and no other harmful by-products were detected. The thus-obtained 2,5-FDCA was applied for the preparation of poly(ethylene furandicarboxylate) (PEF) of high quality in terms of high molecular weight and good appearance. |
| 学科主题 | Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| 公开日期 | 2018-12-04 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/17469]  |
| 专题 | 2018专题 |
| 推荐引用方式 GB/T 7714 | Zhu, Jin,Liu, Xiao-Qing,Wang, Jing-Gang. From Furan to High Quality Bio-based Poly(ethylene furandicarboxylate)[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2018,36(6):720-727. |
| APA | Zhu, Jin,Liu, Xiao-Qing,&Wang, Jing-Gang.(2018).From Furan to High Quality Bio-based Poly(ethylene furandicarboxylate).CHINESE JOURNAL OF POLYMER SCIENCE,36(6),720-727. |
| MLA | Zhu, Jin,et al."From Furan to High Quality Bio-based Poly(ethylene furandicarboxylate)".CHINESE JOURNAL OF POLYMER SCIENCE 36.6(2018):720-727. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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