Construction of Porous Aromatic Frameworks with Exceptional Porosity via Building Unit Engineering
文献类型：期刊论文
| 作者 | Zhu, Guangshan3,4; Deng, Feng1; Xu, Jun1; Mu, Xin4; Li, Jialu4; Zhu, Youliang2; Tian, Yuyang3; Sun, Fuxing4; Ren, Hao4; Li, Meiping4 |
| 刊名 | ADVANCED MATERIALS
 |
| 出版日期 | 2018-10-25 |
| 卷号 | 30期号:43页码:7 |
| 关键词 | adsorption building unit engineering methane organic frameworks porous materials |
| ISSN号 | 0935-9648 |
| DOI | 10.1002/adma.201804169 |
| 英文摘要 | The construction of excellent porous organic frameworks (POFs) with high surface areas and stability is always a tremendous challenge in synthetic chemistry. The geometric configuration and reactive group of building unit are crucial factors to influence the structure and porosity of the resulting product. Herein, the design, synthesis, and characterization of two porous aromatic framework (PAF) materials, named PAF-100 and PAF-101, are reported via a strategy of building unit engineering. PAF-100 and PAF-101 present high Brunauer-Emmett-Teller surface areas exceeding 5000 m(2) g(-1) and uniform pore size distributions. Furthermore, PAF-100 and PAF-101 show high methane uptake with value of 742 and 622 cm(3) g(-1), respectively, at 298 K and 70 bar. The successful synthesis of PAFs with exceptional porosity from engineered building unit is powerful for constructing highly porous POFs. |
| WOS关键词 | METAL-ORGANIC FRAMEWORKS ; POLYMER NETWORKS ; METHANE STORAGE ; SURFACE-AREA ; GAS-UPTAKE ; DESIGN ; STABILITY ; SOLIDS ; ADSORPTION ; PRESSURE |
| 资助项目 | National Natural Science Foundation of China[91622106] ; National Natural Science Foundation of China[21531003] ; National Basic Research Program of China (973 Program)[2012CB821700] ; National Basic Research Program of China (973 Program)[2014CB931800] ; Major International (Regional) Joint Research Project of NSFC[21120102034] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000448786000026 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; National Basic Research Program of China (973 Program) ; Major International (Regional) Joint Research Project of NSFC ; National Natural Science Foundation of China ; National Basic Research Program of China (973 Program) ; Major International (Regional) Joint Research Project of NSFC ; National Natural Science Foundation of China ; National Basic Research Program of China (973 Program) ; Major International (Regional) Joint Research Project of NSFC ; National Natural Science Foundation of China ; National Basic Research Program of China (973 Program) ; Major International (Regional) Joint Research Project of NSFC |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/13182]  |
| 专题 | 中国科学院武汉物理与数学研究所 |
| 通讯作者 | Zhu, Guangshan |
| 作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, Natl Ctr Magnet Resonance Wuhan, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchu 130022, Peoples R China 3.Northeast Normal Univ, Fac Chem, Key Lab Polyoxometalate Sci, Minist Educ, Changchun 130024, Jilin, Peoples R China 4.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Guangshan,Deng, Feng,Xu, Jun,et al. Construction of Porous Aromatic Frameworks with Exceptional Porosity via Building Unit Engineering[J]. ADVANCED MATERIALS,2018,30(43):7. |
| APA | Zhu, Guangshan.,Deng, Feng.,Xu, Jun.,Mu, Xin.,Li, Jialu.,...&Li, Meiping.(2018).Construction of Porous Aromatic Frameworks with Exceptional Porosity via Building Unit Engineering.ADVANCED MATERIALS,30(43),7. |
| MLA | Zhu, Guangshan,et al."Construction of Porous Aromatic Frameworks with Exceptional Porosity via Building Unit Engineering".ADVANCED MATERIALS 30.43(2018):7. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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