Activating Aromatic Rings as Na-Ion Storage Sites to Achieve High Capacity
文献类型：期刊论文
| 作者 | Huang, Yun-Hui5; Liu, Jianjun4; Kang, Litao3; Zeng, Rui5; Huang, Ying5; Liu, Qing5; Li, Yuyu5; Zhang, Yan1; Yang, Jun1; Lei, Danni2 |
| 刊名 | CHEM
 |
| 出版日期 | 2018-10-11 |
| 卷号 | 4期号:10页码:2463-2478 |
| ISSN号 | 2451-9294 |
| DOI | 10.1016/j.chempr.2018.08.015 |
| 英文摘要 | Similar to graphite and graphene, aromatic rings are ultra-stable configurations with highly delocalized sp(2)-hybridized electrons, which are the basic units for most organic electrode materials. However, the aromatic rings in organic electrode materials are inaccessible for Nation storage. Here, we have designed a wavy-layered 3D structure of metal-organic compound zinc perylenetetracar boxylates (Zn-PTCA) with stretched space between adjacent perylene planes, which enables aromatic rings activated as Nation storage sites. Such Zn-PTCA delivers a high specific capacity of 357 mAh g(-1) at a current density of 50 mA g(-1) within the potential range of 0.01-2 V versus Na+/Na, corresponding to an eight-electron-transfer process. Experiments and calculations revealed that both C=O groups and aromatic rings are involved in the Na insertion processes. We believe that the present strategy can open up an avenue for developing a big family of 3D open-framework-structured organic materials for application in high-capacity Nation batteries. |
| WOS关键词 | GENERALIZED GRADIENT APPROXIMATION ; DENSITY-FUNCTIONAL THEORY ; TOTAL-ENERGY CALCULATIONS ; WAVE BASIS-SET ; COORDINATION POLYMERS ; THERMAL-PROPERTIES ; BATTERIES ; PERFORMANCE ; ELECTRODE ; ANODES |
| 资助项目 | National Natural Science Foundation of China[51702111] ; National Natural Science Foundation of China[51632001] ; National Natural Science Foundation of China[21573272] ; Program for Changjiang Scholars and Innovative Research Team in University[IRT14R18] ; project of the Innovative Group of Guangdong Province[2014ZT05N013] ; China Postdoctoral Science Foundation[2016M592328] ; Science and Technology Commission of Shanghai Municipality[16DZ2260600] ; Science and Technology Commission of Shanghai Municipality[18511109402] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000447051500025 |
| 出版者 | CELL PRESS |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in University ; Program for Changjiang Scholars and Innovative Research Team in University ; project of the Innovative Group of Guangdong Province ; project of the Innovative Group of Guangdong Province ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Science and Technology Commission of Shanghai Municipality ; Science and Technology Commission of Shanghai Municipality ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in University ; Program for Changjiang Scholars and Innovative Research Team in University ; project of the Innovative Group of Guangdong Province ; project of the Innovative Group of Guangdong Province ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Science and Technology Commission of Shanghai Municipality ; Science and Technology Commission of Shanghai Municipality ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in University ; Program for Changjiang Scholars and Innovative Research Team in University ; project of the Innovative Group of Guangdong Province ; project of the Innovative Group of Guangdong Province ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Science and Technology Commission of Shanghai Municipality ; Science and Technology Commission of Shanghai Municipality ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in University ; Program for Changjiang Scholars and Innovative Research Team in University ; project of the Innovative Group of Guangdong Province ; project of the Innovative Group of Guangdong Province ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Science and Technology Commission of Shanghai Municipality ; Science and Technology Commission of Shanghai Municipality |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/13231]  |
| 专题 | 中国科学院武汉物理与数学研究所 |
| 通讯作者 | Huang, Yun-Hui; Liu, Jianjun; Fang, Chun |
| 作者单位 | 1.Chinese Acad Sci, Natl Ctr Magnet Resonance Wuhan, Key Lab Magnet Resonance Biol Syst,Wuhan Inst Phy, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China 2.Tsinghua Univ, Grad Sch Shenzhen, Engn Lab Next Generat Power & Energy Storage Batt, Shenzhen 518055, Peoples R China 3.Taiyuan Univ Technol, Coll Mat Sci & Engn, Lab Green Energy Mat & Storage Syst, Taiyuan 030024, Shanxi, Peoples R China 4.Chinese Acad Sci, State Key Lab High Performance Ceram & Superfine, Shanghai Inst Ceram, 1295 Dingxi Rd, Shanghai 200050, Peoples R China 5.Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mould Technol, Wuhan 430074, Hubei, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Yun-Hui,Liu, Jianjun,Kang, Litao,et al. Activating Aromatic Rings as Na-Ion Storage Sites to Achieve High Capacity[J]. CHEM,2018,4(10):2463-2478. |
| APA | Huang, Yun-Hui.,Liu, Jianjun.,Kang, Litao.,Zeng, Rui.,Huang, Ying.,...&Liu, Yaojun.(2018).Activating Aromatic Rings as Na-Ion Storage Sites to Achieve High Capacity.CHEM,4(10),2463-2478. |
| MLA | Huang, Yun-Hui,et al."Activating Aromatic Rings as Na-Ion Storage Sites to Achieve High Capacity".CHEM 4.10(2018):2463-2478. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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