A Heterogeneous Metal-Free Catalyst for Hydrogenation: Lewis Acid-Base Pairs Integrated into a Carbon Lattice
文献类型：期刊论文
| 作者 | Su, Dang Sheng1,4; Zheng, Anmin3; Sun, Xiaoyan2; Qiao, Yunxiang5; Yi, Xianfeng3; Huang, Xing4; Ding, Yuxiao5 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2018-10-15 |
| 卷号 | 57期号:42页码:13800-13804 |
| 关键词 | heterogeneous catalysis hydrogenation Lewis pairs metal-free catalysis nanocarbons |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201803977 |
| 英文摘要 | Designing heterogeneous metal-free catalysts for hydrogenation is a long-standing challenge in catalysis. Nanodiamond-based carbon materials were prepared that are surface-doped with electron-rich nitrogen and electron-deficient boron. The two heteroatoms are directly bonded to each other to form unquenched Lewis pairs with infinite pi-electron donation from the surrounding graphitic structure. Remarkably, these Lewis pairs can split H-2 to form H+/H- pairs, which subsequently serve as the active species for hydrogenation of different substrates. This unprecedented finding sheds light on the uptake of H-2 across carbon-based materials and suggests that dual Lewis acidity-basicity on the carbon surface may be used to heterogeneously activate a variety of small molecules. |
| WOS关键词 | SOLID-STATE NMR ; PROBE MOLECULE ; IONIC LIQUIDS ; ACTIVATION ; SITES ; TRIMETHYLPHOSPHINE ; NANOTUBES ; PYRROLE ; SURFACE |
| 资助项目 | NSFC of China[21473223] ; Talents Innovation Project of Dalian[2016RD04] ; NSFC[21522310] ; NSFC[21473244] ; NSF of Hubei[2018CFA009] ; Key Research Program of Frontier Sciences CAS[QYZDB-SSW-SLH026] ; Max Planck Society |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000446826200012 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | NSFC of China ; NSFC of China ; Talents Innovation Project of Dalian ; Talents Innovation Project of Dalian ; NSFC ; NSFC ; NSF of Hubei ; NSF of Hubei ; Key Research Program of Frontier Sciences CAS ; Key Research Program of Frontier Sciences CAS ; Max Planck Society ; Max Planck Society ; NSFC of China ; NSFC of China ; Talents Innovation Project of Dalian ; Talents Innovation Project of Dalian ; NSFC ; NSFC ; NSF of Hubei ; NSF of Hubei ; Key Research Program of Frontier Sciences CAS ; Key Research Program of Frontier Sciences CAS ; Max Planck Society ; Max Planck Society ; NSFC of China ; NSFC of China ; Talents Innovation Project of Dalian ; Talents Innovation Project of Dalian ; NSFC ; NSFC ; NSF of Hubei ; NSF of Hubei ; Key Research Program of Frontier Sciences CAS ; Key Research Program of Frontier Sciences CAS ; Max Planck Society ; Max Planck Society ; NSFC of China ; NSFC of China ; Talents Innovation Project of Dalian ; Talents Innovation Project of Dalian ; NSFC ; NSFC ; NSF of Hubei ; NSF of Hubei ; Key Research Program of Frontier Sciences CAS ; Key Research Program of Frontier Sciences CAS ; Max Planck Society ; Max Planck Society |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/13295]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 通讯作者 | Su, Dang Sheng; Qiao, Yunxiang |
| 作者单位 | 1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Tech Univ Berlin, Dept Chem, D-10623 Berlin, Germany 3.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Hubei, Peoples R China 4.Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany 5.Max Planck Inst Chem Energiekonvers, Stiftstr 34-36, D-45470 Mulheim, Germany |
| 推荐引用方式 GB/T 7714 | Su, Dang Sheng,Zheng, Anmin,Sun, Xiaoyan,et al. A Heterogeneous Metal-Free Catalyst for Hydrogenation: Lewis Acid-Base Pairs Integrated into a Carbon Lattice[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(42):13800-13804. |
| APA | Su, Dang Sheng.,Zheng, Anmin.,Sun, Xiaoyan.,Qiao, Yunxiang.,Yi, Xianfeng.,...&Ding, Yuxiao.(2018).A Heterogeneous Metal-Free Catalyst for Hydrogenation: Lewis Acid-Base Pairs Integrated into a Carbon Lattice.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(42),13800-13804. |
| MLA | Su, Dang Sheng,et al."A Heterogeneous Metal-Free Catalyst for Hydrogenation: Lewis Acid-Base Pairs Integrated into a Carbon Lattice".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.42(2018):13800-13804. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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