An effective strategy for controlling the morphology of high-performance non-fullerene polymer solar cells without post-treatment: employing bare rigid aryl rings as lever arms in new asymmetric benzodithiophene
文献类型：期刊论文
| 作者 | Liu, Deyu1,2; Zhang, Kaili1; Zhong, Yaqian1; Gu, Chunyang1; Li, Yonghai1; Yang, Renqiang1 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2018-10-07 |
| 卷号 | 6期号:37页码:18125-18132 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/c8ta07134a |
| 英文摘要 | Almost all high-performance non-fullerene polymer solar cells (NF-PSCs) require the optimization of the morphologies of active layers using additional complicated treatments, such as solvent additive processing and thermal annealing. There are still no guidelines currently available regarding controlling the morphologies of polymer donor and fused-ring acceptor blends from a structural point of view to avoid additional post-treatments. Here, we propose an efficient strategy to design polymers that can generate preferred morphologies and then be used to fabricate as-cast high-performance NF-PSCs. New asymmetric benzodithiophene (BDT) building blocks are employed to construct these polymers. The thienylthiol group with a long alkyl chain as one side substituent on BDT can modulate energy levels, broaden absorption spectra and improve solubility. For the key other side chain, bare rigid aryl rings (benzene, naphthalene and biphenyl) are used as lever arms to stir well the elongated acceptor (ITIC) phase and weaken entanglements among polymer chains during the spin-coating process, which enables favorable morphologies without any post-treatments. Finally, the polymer PBDTTAZ-NaPh yielded a power conversion efficiency (PCE) of 11.56%, which is a rare high value for as-cast NF-PSCs. Thus, it would be feasible to employ this proposed strategy to design high-performance NF-PSCs without post-treatment that meet the requirements for future industry-scale production. |
| WOS关键词 | OPEN-CIRCUIT VOLTAGE ; ELECTRON-ACCEPTOR ; PHOTOVOLTAIC DEVICES ; SIDE-CHAIN ; ORGANIC PHOTOVOLTAICS ; EFFICIENCY ; DESIGN ; ALKYLTHIO ; STABILITY ; ENABLES |
| 资助项目 | Natural Science Foundation of China[51573205] ; Natural Science Foundation of China[51773220] ; Natural Science Foundation of China[21502205] ; Ministry of Science and Technology of China[2014CB643501] ; DICP QIBEBT[UN201709] ; Dalian National Laboratory for Clean Energy (DNL), CAS |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000448340100029 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | Natural Science Foundation of China ; Ministry of Science and Technology of China ; DICP QIBEBT ; Dalian National Laboratory for Clean Energy (DNL), CAS |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/11216]  |
| 专题 | 中国科学院青岛生物能源与过程研究所 |
| 通讯作者 | Yang, Renqiang |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Deyu,Zhang, Kaili,Zhong, Yaqian,et al. An effective strategy for controlling the morphology of high-performance non-fullerene polymer solar cells without post-treatment: employing bare rigid aryl rings as lever arms in new asymmetric benzodithiophene[J]. JOURNAL OF MATERIALS CHEMISTRY A,2018,6(37):18125-18132. |
| APA | Liu, Deyu,Zhang, Kaili,Zhong, Yaqian,Gu, Chunyang,Li, Yonghai,&Yang, Renqiang.(2018).An effective strategy for controlling the morphology of high-performance non-fullerene polymer solar cells without post-treatment: employing bare rigid aryl rings as lever arms in new asymmetric benzodithiophene.JOURNAL OF MATERIALS CHEMISTRY A,6(37),18125-18132. |
| MLA | Liu, Deyu,et al."An effective strategy for controlling the morphology of high-performance non-fullerene polymer solar cells without post-treatment: employing bare rigid aryl rings as lever arms in new asymmetric benzodithiophene".JOURNAL OF MATERIALS CHEMISTRY A 6.37(2018):18125-18132. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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