Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water
文献类型：期刊论文
| 作者 | Li, Yaru1,2; Guo, Xingcui2 ; Liu, Daosheng1; Mu, Xindong2; Chen, Xiufang2; Shi, Yan1
|
| 刊名 | CATALYSTS
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 8期号:5 |
| 关键词 | Furfural Co-ni Catalyst Cyclopentanone Cyclopentanol Hydrogenation |
| ISSN号 | 2073-4344 |
| DOI | 10.3390/catal8050193 |
| 文献子类 | Article |
| 英文摘要 | Co-Ni catalysts, prepared by a typical wetness impregnation method, can selectively convert furfural (FFA) to cyclopentanone (CPO) or cyclopentanol (CPL) in water, respectively. The catalytic performance depends strongly on the support. It is also strongly influenced by the Co-Ni loadings of the catalyst. The 10%Co-10%Ni/TiO2 catalyst showed the highest selectivity toward CPO (53.3%) with almost complete FFA conversion, and the main product was CPL (45.4%) over 20%Co/TiO2 at the optimized conditions (150 degrees C, 4 MPa H-2, 4 h). The surface morphology, surface area, composition and reducibility properties of these catalysts were fully characterized by XRD, H-2-TPR, ICP-AES and SEM. The factors that influenced the activity of catalysts were also investigated in detail. Additionally, the stability of catalyst for the hydrogenative rearrangement of FFA was studied. |
| WOS关键词 | BIMETALLIC CATALYSTS ; COBALT CATALYSTS ; SUPPORTED COBALT ; CARBON ; HYDROGENATION ; CHEMICALS ; TRANSFORMATION ; REARRANGEMENT ; NANOTUBES ; COMPOUND |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000435191500022 |
| 出版者 | MDPI |
| 资助机构 | National Natural Science Foundation of China(21433001 ; key basic research project of Shandong Natural Science Foundation(ZR201708240147) ; Young Taishan Scholars Program of Shandong Province(tsqn 20161052) ; 21406251) |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/11377]  |
| 专题 | 中国科学院青岛生物能源与过程研究所 |
| 通讯作者 | Guo, Xingcui; Shi, Yan |
| 作者单位 | 1.Liaoning Shihua Univ, Coll Chem Chem Engn & Environm Engn, 1 Dandong Rd, Fushun 113001, Liaoning, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yaru,Guo, Xingcui,Liu, Daosheng,et al. Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water[J]. CATALYSTS,2018,8(5). |
| APA | Li, Yaru,Guo, Xingcui,Liu, Daosheng,Mu, Xindong,Chen, Xiufang,&Shi, Yan.(2018).Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water.CATALYSTS,8(5). |
| MLA | Li, Yaru,et al."Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water".CATALYSTS 8.5(2018). |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。