Controlled Hydrodeoxygenation of Phenolic Components in Pyrolysis Bio-oil to Arenes
文献类型：期刊论文
| 作者 | Jiang, Guangce1,2 ; Hu, Yinghui1; Xu, Guoqiang1; Mu, Xindong1; Liu, Huizhou1
|
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 6期号:5页码:5772-5783 |
| 关键词 | Controlled Hydrodeoxygenation Phenolic Compounds Ru-wox/zro2 Catalyst Pyrolysis Bio-oil |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.7b03276 |
| 文献子类 | Article |
| 英文摘要 | Hydrodeoxygenation of phenolic components in pyrolysis bio-oil is considered to be a potential strategy for producing renewable aromatic chemicals. The key issue of this process is the establishment of an effective catalytic system that can cleave the C-Ar-O bonds without affecting the aromatic structure. To achieve this goal, an efficient heterogeneous catalyst with solid acid support (WOx/ZrO2) and active metal (Ru) was prepared in this study. The Ru WOx/ZrO2 catalyst can effectively convert model phenolic compounds into aromatic hydrocarbons. For a mixed phenolic sample, the conversion to and selectivity for arenes were all around 90%. The good selectivity was proved to be strongly related to the surface adsorption and acid properties of the catalyst as well as the reaction pathway. Moreover, the hydrodeoxygenation of a pretreated bio-oil was also conducted and presented a satisfactory yield of arenes at 240 degrees C with 1 MPa of H-2 reacted for 5 h. The depolymerization of high-molecular-weight phenolic oligomers was found to be significant during the catalytic process, which further enhanced the yield of aromatic monomers. |
| WOS关键词 | SOLID ACID CATALYSTS ; BIFUNCTIONAL CATALYSTS ; RU NANOPARTICLES ; LIGNIN ; BIOMASS ; KINETICS ; TUNGSTEN ; HYDROGENATION ; REDUCTION ; ZIRCONIA |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000431927500015 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Boeing ; National Natural Science Foundation of China(21273260 ; Shandong Provincial Natural Science Foundation for Distinguished Young Scholar(JQ201305) ; Youth Innovation Promotion Association CAS(2015168) ; Taishan Scholars Climbing Program of Shandong(tspd20150210) ; Young Taishan Scholars Program of Shandong Province(tsqn20161052) ; 21433001) |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/11401]  |
| 专题 | 中国科学院青岛生物能源与过程研究所 |
| 通讯作者 | Xu, Guoqiang; Mu, Xindong |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, 189 Songling Rd, Qingdao 266101, Shandong, Peoples R China 2.Henan Agr Univ, Sch Sci, Dept Appl Chem, 63 Nongye Rd, Zhengzhou 450002, Henan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Guangce,Hu, Yinghui,Xu, Guoqiang,et al. Controlled Hydrodeoxygenation of Phenolic Components in Pyrolysis Bio-oil to Arenes[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2018,6(5):5772-5783. |
| APA | Jiang, Guangce,Hu, Yinghui,Xu, Guoqiang,Mu, Xindong,&Liu, Huizhou.(2018).Controlled Hydrodeoxygenation of Phenolic Components in Pyrolysis Bio-oil to Arenes.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,6(5),5772-5783. |
| MLA | Jiang, Guangce,et al."Controlled Hydrodeoxygenation of Phenolic Components in Pyrolysis Bio-oil to Arenes".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 6.5(2018):5772-5783. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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