The interfacial evolution between polycarbonate-based polymer electrolyte and Li-metal anode
文献类型：期刊论文
| 作者 | Wang, Chen1,2; Zhang, Huanrui1; Li, Jiedong1; Chai, Jingchao1,2; Dong, Shanmu1; Cui, Guanglei1
|
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2018-09-01 |
| 卷号 | 397页码:157-161 |
| 关键词 | Interface Evolution Polymer electrolytes Li-metal anode |
| ISSN号 | 0378-7753 |
| DOI | 10.1016/j.jpowsour.2018.07.008 |
| 英文摘要 | Solid polymer electrolyte is strongly considered to be one of the key materials to solve safety problem of high energy lithium batteries caused by flammable liquid organic carbonate solvent, while the development and application of solid polymer electrolytes are seriously restricted by the low ambient temperature ionic conductivity. Recently, aliphatic polycarbonate-based electrolytes have been reported to possess high ionic conductivity at ambient temperature. Herein we choose poly (propylene carbonate) as a model to investigate the origin of the high ionic conductivity of polycarbonate-based polymer electrolytes. Our results prove that poly (propylene carbonate) degrades to micromolecular segments when contacts with Li-metal anode. The depolymerization products can infiltrate the interface and swell the electrolyte to develop the amorphous state so as to reduce both interfacial and bulk resistance. As scaffold of the electrolyte, cellulose can limit this reaction at the interface by physical obstruction. The hydroxyl units can also quench the lithium alkoxide intermediate to suppress further degradation, guaranteeing the security of the system. This study provides a profound understanding of the composition, reaction and evolution of the interface between polymer electrolyte and Li-metal anode, which sheds new light on the interface construction of ambient-temperature solid-state lithium metal batteries. |
| WOS关键词 | RECHARGEABLE BATTERIES ; PROPYLENE CARBONATE ; IONIC-CONDUCTIVITY ; POLY(ETHYLENE OXIDE) ; LITHIUM BATTERIES ; INTERPHASE LAYER ; FIBERS ; LIQUID ; SALTS |
| 资助项目 | National Science Fund for Distinguished Young Scholars[51625204] ; National Natural Science Foundation of China[51703236] ; Youth Innovation Promotion Association of CAS[2016193] ; China Postdoctoral Science Foundation[2017M612366] ; Key research and development plan of Shandong Province P. R. China[2018GGX104016] ; Key Scientific and Technological Innovation Project of Shandong[2017CXZC0505] |
| WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000445317900020 |
| 出版者 | ELSEVIER SCIENCE BV |
| 资助机构 | National Science Fund for Distinguished Young Scholars ; National Natural Science Foundation of China ; Youth Innovation Promotion Association of CAS ; China Postdoctoral Science Foundation ; Key research and development plan of Shandong Province P. R. China ; Key Scientific and Technological Innovation Project of Shandong |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/11646]  |
| 专题 | 中国科学院青岛生物能源与过程研究所 |
| 通讯作者 | Dong, Shanmu; Cui, Guanglei |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Ind Energy Storage Technol Inst, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Chen,Zhang, Huanrui,Li, Jiedong,et al. The interfacial evolution between polycarbonate-based polymer electrolyte and Li-metal anode[J]. JOURNAL OF POWER SOURCES,2018,397:157-161. |
| APA | Wang, Chen,Zhang, Huanrui,Li, Jiedong,Chai, Jingchao,Dong, Shanmu,&Cui, Guanglei.(2018).The interfacial evolution between polycarbonate-based polymer electrolyte and Li-metal anode.JOURNAL OF POWER SOURCES,397,157-161. |
| MLA | Wang, Chen,et al."The interfacial evolution between polycarbonate-based polymer electrolyte and Li-metal anode".JOURNAL OF POWER SOURCES 397(2018):157-161. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。