In Situ Determination of Bisphenol A in Beverage Using a Molybdenum Selenide/Reduced Graphene Oxide Nanoparticle Composite Modified Glassy Carbon Electrode
文献类型：期刊论文
| 作者 | Shi, Rongguang1; Liang, Jing2; Zhao, Zongshan2 ; Liu, Yi3; Liu, Aifeng2
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| 刊名 | SENSORS
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| 出版日期 | 2018-05-01 |
| 卷号 | 18期号:5页码:10 |
| 关键词 | electrochemical sensor molybdenum selenide reduced graphene oxide bisphenol A beverage |
| ISSN号 | 1424-8220 |
| DOI | 10.3390/s18051660 |
| 英文摘要 | Due to the endocrine disturbing effects of bisphenol A (BPA) on organisms, rapid detection has become one of the most important techniques for monitoring its levels in the aqueous solutions associated with plastics and human beings. In this paper, a glassy carbon electrode (GCE) modified with molybdenum selenide/reduced graphene oxide (MoSe2/rGO) was fabricated for in situ determination of bisphenol A in several beverages. The surface area of the electrode dramatically increases due to the existence of ultra-thin nanosheets in a flower-like structure of MoSe2. Adding phosphotungstic acid in the electrolyte can significantly enhance the repeatability (RSD = 0.4%) and reproducibility (RSD = 2.2%) of the electrode. Under the optimized condition (pH = 6.5), the linear range of BPA was from 0.1 mu M-100 mu M and the detection limit was 0.015 mu M (S/N = 3). When using the as-prepared electrode for analyzing BPA in beverage samples without any pretreatments, the recoveries ranged from 98-107%, and the concentrations were from below the detection limit to 1.7 mu M, indicating its potential prospect for routine analysis of BPA. |
| WOS关键词 | ELECTROCHEMICAL SENSOR ; MASS-SPECTROMETRY ; PHOSPHOTUNGSTIC ACID ; SENSITIVE DETECTION ; PASTE ELECTRODE ; WASTE-WATER ; CHROMATOGRAPHY ; ALKYLPHENOLS ; REDUCTION ; PHTHALATE |
| 资助项目 | National Natural Science Foundation of China[21607161] ; National Natural Science Foundation of China[21402192] ; Open Fund of the Key Laboratory for Environmental Factors Control of Agro-product Quality Safety, Ministry of Agriculture |
| WOS研究方向 | Chemistry ; Electrochemistry ; Instruments & Instrumentation |
| 语种 | 英语 |
| WOS记录号 | WOS:000435580300359 |
| 出版者 | MDPI |
| 资助机构 | National Natural Science Foundation of China ; Open Fund of the Key Laboratory for Environmental Factors Control of Agro-product Quality Safety, Ministry of Agriculture |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/12367]  |
| 专题 | 中国科学院青岛生物能源与过程研究所 |
| 通讯作者 | Zhao, Zongshan; Liu, Yi |
| 作者单位 | 1.Minist Agr, Agroenvironm Protect Inst, Key Lab Environm Factors Control Agroprod Qual Sa, Tianjin 300191, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China 3.Yantai Univ, Sch Chem & Chem Engn, Yantai 264005, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Rongguang,Liang, Jing,Zhao, Zongshan,et al. In Situ Determination of Bisphenol A in Beverage Using a Molybdenum Selenide/Reduced Graphene Oxide Nanoparticle Composite Modified Glassy Carbon Electrode[J]. SENSORS,2018,18(5):10. |
| APA | Shi, Rongguang,Liang, Jing,Zhao, Zongshan,Liu, Yi,&Liu, Aifeng.(2018).In Situ Determination of Bisphenol A in Beverage Using a Molybdenum Selenide/Reduced Graphene Oxide Nanoparticle Composite Modified Glassy Carbon Electrode.SENSORS,18(5),10. |
| MLA | Shi, Rongguang,et al."In Situ Determination of Bisphenol A in Beverage Using a Molybdenum Selenide/Reduced Graphene Oxide Nanoparticle Composite Modified Glassy Carbon Electrode".SENSORS 18.5(2018):10. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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