Local-structure change rendered by electronic localization-delocalization transition in cerium-based metallic glasses
文献类型：期刊论文
| 作者 | Luo, Qiang; Schwarz, Bjoern1; Swarbrick, Janine C.; Bednarcik, Jozef3; Zhu, Yingcai4; Tang, Meibo5; Zheng, Lirong4; Li, Ran6; Shen, Jun; Eckert, Juergen7,8 |
| 刊名 | PHYSICAL REVIEW B
 |
| 出版日期 | 2018 |
| 卷号 | 97期号:6 |
| ISSN号 | 2469-9950 |
| DOI | 10.1103/PhysRevB.97.064104 |
| 英文摘要 | With increasing temperature, metallic glasses (MGs) undergo first glass transitionwithout pronounced structural change and then crystallization with distinct variation in structure and properties. The present study shows a structural change of short-range order induced by an electron-delocalization transition, along with an unusual large-volume shrinkage in Ce-based MGs. An f-electron localization-delocalization transition with thermal hysteresis is observed from the temperature dependence of x-ray absorption spectroscopy and resonant inelastic x-ray scattering spectra, indicating an inheritance of the 4f configuration of pure Ce. However, the delocalization transition becomes broadened due to the local structural heterogeneity and related fluctuation of 4f levels in the Ce-based MGs. The amorphous structure regulated 4f delocalization of Ce leads to bond shortening and abnormal structure change of the topological and chemical short-range orders. Due to the hierarchical bonding nature, the structure should change in a similar manner on different length scales (but not isostructurally like the Ce metal) in Ce-based MGs. |
| 学科主题 | Physics, Condensed Matter |
| WOS记录号 | WOS:000424744900005 |
| 出版者 | AMER PHYSICAL SOC |
| 资助机构 | The financial support from the National Natural Science Foundation of China (Grants No. 51371127 and No. 51274151), as well as additional support by the German Science Foundation under the Leibniz Program (Grant No. EC 111/26-1) and the ERC Advanced Grant INTELHYB (Grant No. ERC-2013-ADG-340025) is gratefully acknowledged. The authors would like to thank the European Synchrotron Radiation Facility (ESRF) in Grenoble, France, DESY(Hamburg, Germany), and the Beijing Synchrotron Radiation Facility (BSRF) in Beijing, China, for use of the synchrotron radiation facilities. Qiang Luo would like to thank the Alexander von Humboldt Foundation for financial support. The experimental assistance of Dr. Pieter Glatzel at ESRF and Dr. Liangliang Li at Center for High Pressure Science & Technology Advanced Research China is greatly appreciated. ; The financial support from the National Natural Science Foundation of China (Grants No. 51371127 and No. 51274151), as well as additional support by the German Science Foundation under the Leibniz Program (Grant No. EC 111/26-1) and the ERC Advanced Grant INTELHYB (Grant No. ERC-2013-ADG-340025) is gratefully acknowledged. The authors would like to thank the European Synchrotron Radiation Facility (ESRF) in Grenoble, France, DESY(Hamburg, Germany), and the Beijing Synchrotron Radiation Facility (BSRF) in Beijing, China, for use of the synchrotron radiation facilities. Qiang Luo would like to thank the Alexander von Humboldt Foundation for financial support. The experimental assistance of Dr. Pieter Glatzel at ESRF and Dr. Liangliang Li at Center for High Pressure Science & Technology Advanced Research China is greatly appreciated. |
| 源URL | [http://ir.sic.ac.cn/handle/331005/24492]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.Tongji Univ, Sch Mat Sci & Engn, Shanghai 201804, Peoples R China 2.Karlsruhe Inst Technol KIT, Inst Appl Mat IAM, D-76344 Eggenstein Leopoldshafen, Germany 3.Swarbrick, Janine C.] European Synchrotron Radiat Facil ESRF, BP22,6 Rue Jules Horowitz, F-38043 Grenoble, France 4.Deutsch Elektronen Synchrotron DESY, Notkestr 85, D-22607 Hamburg, Germany 5.Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China 6.Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Transparent & Optofunct Inorgan Mat, Shanghai 200050, Peoples R China 7.Beihang Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Aerosp Mat & Performance, Beijing 100191, Peoples R China 8.Austrian Acad Sci, Erich Schmid Inst Mat Sci, Jahnstr 12, A-8700 Leoben, Austria 9.Univ Leoben, Dept Mat Phys, Jahnstr 12, A-8700 Leoben, Austria |
| 推荐引用方式 GB/T 7714 | Luo, Qiang,Schwarz, Bjoern,Swarbrick, Janine C.,et al. Local-structure change rendered by electronic localization-delocalization transition in cerium-based metallic glasses[J]. PHYSICAL REVIEW B,2018,97(6). |
| APA | Luo, Qiang.,Schwarz, Bjoern.,Swarbrick, Janine C..,Bednarcik, Jozef.,Zhu, Yingcai.,...&Eckert, Juergen.(2018).Local-structure change rendered by electronic localization-delocalization transition in cerium-based metallic glasses.PHYSICAL REVIEW B,97(6). |
| MLA | Luo, Qiang,et al."Local-structure change rendered by electronic localization-delocalization transition in cerium-based metallic glasses".PHYSICAL REVIEW B 97.6(2018). |
入库方式： OAI收割
来源：上海硅酸盐研究所
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