Kinetically controlled synthesis of Cu nanowires with tunable diameters and their applications in transparent electrodes
文献类型:期刊论文
作者 | Wang, Xiao; Wang, Ranran; Shi, Liangjing; Sun, Jing |
刊名 | JOURNAL OF MATERIALS CHEMISTRY C
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出版日期 | 2018 |
卷号 | 6期号:5页码:1048 |
ISSN号 | 2050-7526 |
DOI | 10.1039/c7tc05038k |
英文摘要 | One-dimensional metallic nanostructures have attracted ever increasing attention in recent years due to their potential applications in transparent electrodes, catalysts, surface enhanced resonance scattering (SERS) based sensors and electric heating elements. The controllable synthesis of high quality metal nanowires is of great importance for the optimization of devices based on metal nanowires. However, due to the intrinsic complexity of one-pot organic reaction systems, the reaction mechanism is still yet to be understood, which severely holds back the efforts towards the controllable synthesis of high quality nanowires. Herein, a two-step method for the synthesis of high-quality Cu nanowires with tunable diameters is proposed. The mechanism of a typical synthesis procedure is discussed through analyzing the apparent phenomena and intermediate products. Kinetically controlled synthesis is achieved by adjusting the species and concentration of halide ions to synthesize high-purity Cu nanowires with tunable diameters ranging from 20 to 90 nm. Electrodes with superior conductivity (FoM similar to 140, 11 Omega sq(-1)@80%) are constructed and characterized on the basis of the Cu nanowires synthesized through this method. Red shifts in the LSPR peaks of Cu nanowire dispersions and increments in the haze factors of nanowire electrodes are observed as the average diameter of Cu nanowires increases. The method is also successfully expanded to the synthesis of Ag nanowires with tunable diameters. |
学科主题 | Materials Science, Multidisciplinary ; Physics, Applied |
WOS记录号 | WOS:000424007200014 |
出版者 | ROYAL SOC CHEMISTRY |
资助机构 | This work was financially supported by the National Natural Science Foundation of China (Grant No. 61301036), the Youth Innovation Promotion Association CAS (2014226), Shanghai Key Basic Research Project (Grant No. 16JC1402300) and the Major State Research Development Program of China (2016YFA0203000). ; This work was financially supported by the National Natural Science Foundation of China (Grant No. 61301036), the Youth Innovation Promotion Association CAS (2014226), Shanghai Key Basic Research Project (Grant No. 16JC1402300) and the Major State Research Development Program of China (2016YFA0203000). |
源URL | [http://ir.sic.ac.cn/handle/331005/24496] ![]() |
专题 | 中国科学院上海硅酸盐研究所 |
作者单位 | Chinese Acad Sci, State Key Lab High Performance Ceram & Superfine, Shanghai Inst Ceram, Beijing, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Xiao,Wang, Ranran,Shi, Liangjing,et al. Kinetically controlled synthesis of Cu nanowires with tunable diameters and their applications in transparent electrodes[J]. JOURNAL OF MATERIALS CHEMISTRY C,2018,6(5):1048, 1056. |
APA | Wang, Xiao,Wang, Ranran,Shi, Liangjing,&Sun, Jing.(2018).Kinetically controlled synthesis of Cu nanowires with tunable diameters and their applications in transparent electrodes.JOURNAL OF MATERIALS CHEMISTRY C,6(5),1048. |
MLA | Wang, Xiao,et al."Kinetically controlled synthesis of Cu nanowires with tunable diameters and their applications in transparent electrodes".JOURNAL OF MATERIALS CHEMISTRY C 6.5(2018):1048. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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