A Thermally Decomposable Template Route to Synthesize Nitrogen-Doped Wrinkled Carbon Nanosheets as Highly Efficient and Stable Electrocatalysts for the Oxygen Reduction Reaction
文献类型：期刊论文
| 作者 | Gu, Daguo; Wang, Fangfang1; Yan, Kang2; Ma, Ruguang1; Wang, Jiacheng1 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2018 |
| 卷号 | 6期号:2页码:1951 |
| 关键词 | Thermal decomposition Biomass Graphene Nitrogen doping Electrocatalysts Oxygen reduction reaction |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.7b03370 |
| 英文摘要 | We successfully developed a thermally decomposable template route to prepare wrinkled carbon nanosheets with a high level of nitrogen functional moieties by direct carbonization of biomass glucose and dicyandiamide as the renewable feedstocks. Confined pyrolysis of glucose within the interlayers of dicyandiamide-derived g-C3N4 as a thermally removable template results in the formation of two-dimensional (2D) wrinkled carbon nanosheets as well as simultaneous high-level nitrogen doping. The textural properties and nitrogen contents could be controlled by adjusting the mass ratio of glucose/dicyandiamide. Among various samples, the sample prepared with the dicyandiamide/glucose mass ratio of 7/1 has optimal activity for the electrocatalytic oxygen reduction (onset potential -0.12 V vs saturated calomel electrode (SCE); limiting current density 4.73 mA/cm(2)) in 0.1 M KOH solution, the half-wave potential of which is only 67 mV larger than that for 20 wt % Pt/C. Moreover, it demonstrates a highly efficient four-electron reaction process, as well as superior durability and tolerance to MeOH crossover to Pt/C. The excellent activity is mainly attributed to the high content of pyridinic and graphitic-N groups, highly graphitized structures, and wrinkled 2D nanostructures, efficiently promoting the increased exposure of actives sites and fast mass/electron transfer. |
| 学科主题 | Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical |
| WOS记录号 | WOS:000424728300048 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | The authors are grateful for financial support from the National Key Research and Development Program of China (2016YFB0700204), Natural Science Foundation of Jiangsu Province (No. BK20140472), NSFC (51602332), Science and Technology Commission of Shanghai Municipality (15520720400, 15YF1413800, 14DZ2261203, 16DZ2260603), and One Hundred Talent Plan of Chinese Academy of Sciences. ; The authors are grateful for financial support from the National Key Research and Development Program of China (2016YFB0700204), Natural Science Foundation of Jiangsu Province (No. BK20140472), NSFC (51602332), Science and Technology Commission of Shanghai Municipality (15520720400, 15YF1413800, 14DZ2261203, 16DZ2260603), and One Hundred Talent Plan of Chinese Academy of Sciences. |
| 源URL | [http://ir.sic.ac.cn/handle/331005/24511]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.Yancheng Inst Technol, Sch Mat Engn, 1 Xiwang Ave, Yancheng 224051, Jiangsu, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, 1295 Dingxi Rd, Shanghai 200050, Peoples R China 3.Nanjing Univ Aeronaut & Astronaut, Coll Aerosp Engn, State Key Lab Mech & Control Mech Struct, 29 Yudao St, Nanjing 210016, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gu, Daguo,Wang, Fangfang,Yan, Kang,et al. A Thermally Decomposable Template Route to Synthesize Nitrogen-Doped Wrinkled Carbon Nanosheets as Highly Efficient and Stable Electrocatalysts for the Oxygen Reduction Reaction[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2018,6(2):1951, 1960. |
| APA | Gu, Daguo,Wang, Fangfang,Yan, Kang,Ma, Ruguang,&Wang, Jiacheng.(2018).A Thermally Decomposable Template Route to Synthesize Nitrogen-Doped Wrinkled Carbon Nanosheets as Highly Efficient and Stable Electrocatalysts for the Oxygen Reduction Reaction.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,6(2),1951. |
| MLA | Gu, Daguo,et al."A Thermally Decomposable Template Route to Synthesize Nitrogen-Doped Wrinkled Carbon Nanosheets as Highly Efficient and Stable Electrocatalysts for the Oxygen Reduction Reaction".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 6.2(2018):1951. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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