High energy storage properties of (Ni1/3Nb2/3)(4+) complex-ion modified (Ba0.85Ca0.15)(Zr0.10Ti0.90)O-3 ceramics
文献类型:期刊论文
作者 | Zhou, Mingxing1; Liang, Ruihong; Zhou, Zhiyong; Xu, Chenhong1; Nie, Xin1; Chen, Xuefeng; Dong, Xianlin |
刊名 | MATERIALS RESEARCH BULLETIN
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出版日期 | 2018 |
卷号 | 98页码:166 |
关键词 | Lead free BCZT Dielectric properties Complex-ion Energy storage |
ISSN号 | 0025-5408 |
DOI | 10.1016/j.materresbull.2017.10.005 |
英文摘要 | In this study, paraelectric ceramics, (Ba0.85Ca0.15)(Zr0.10Ti0.90)(1- x)(Ni1/3Nb2/3)(x)O-3, abbreviated as BCZT-xNN (with x = 0.1, 0.2, 0.3, 0.4) were prepared via a solid-state reaction method. By introducing a B-site complexion, (Ni1/3Nb2/3)(4+), the Curie temperature of the ceramic could be reduced to below room temperature. The effects of this B-site (Ni1/3Nb2/3)(4+) complex-ion substitution on the phase structure, surface microstructure as well as the dielectric, ferroelectric, and energy storage properties of the ceramic were systematically investigated. After adding NN, BCZT-xNN shows a single phase perovskite structure without evidence of a second phase. In addition, we observed high stability with respect to both temperature (-55 to 160 degrees C) and frequency (10(2)-10(7) Hz). Doping with NN produces slim polarization-electric field hysteresis loops and enhanced energy storage properties, while the efficiency decreases. When x = 0.3, the highest energy storage density reached 0.66 J/cm(3) for a high electric field (20 kV/mm), and the respective energy efficiency was 88.1%. These properties indicate that the environmental friendly BCZT-xNN ceramics are promising candidates for commercial energy storage devices. |
学科主题 | Materials Science, Multidisciplinary |
WOS记录号 | WOS:000418221900024 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
资助机构 | This work was supported by the National Natural Science Foundation of China (Grant No. 11574334) and the National Key Basic Research Program of China (973 Program, Grant No. 2015CB057502). ; This work was supported by the National Natural Science Foundation of China (Grant No. 11574334) and the National Key Basic Research Program of China (973 Program, Grant No. 2015CB057502). |
源URL | [http://ir.sic.ac.cn/handle/331005/24528] ![]() |
专题 | 中国科学院上海硅酸盐研究所 |
作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Inorgan Funct Mat & Devices, 1295 Dingxi Rd, Shanghai 200050, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhou, Mingxing,Liang, Ruihong,Zhou, Zhiyong,et al. High energy storage properties of (Ni1/3Nb2/3)(4+) complex-ion modified (Ba0.85Ca0.15)(Zr0.10Ti0.90)O-3 ceramics[J]. MATERIALS RESEARCH BULLETIN,2018,98:166, 172. |
APA | Zhou, Mingxing.,Liang, Ruihong.,Zhou, Zhiyong.,Xu, Chenhong.,Nie, Xin.,...&Dong, Xianlin.(2018).High energy storage properties of (Ni1/3Nb2/3)(4+) complex-ion modified (Ba0.85Ca0.15)(Zr0.10Ti0.90)O-3 ceramics.MATERIALS RESEARCH BULLETIN,98,166. |
MLA | Zhou, Mingxing,et al."High energy storage properties of (Ni1/3Nb2/3)(4+) complex-ion modified (Ba0.85Ca0.15)(Zr0.10Ti0.90)O-3 ceramics".MATERIALS RESEARCH BULLETIN 98(2018):166. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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