Structure, phase transition behavior, and electrical properties of Pb-0.99(SnxZr0.95-xTi0.05)(0.98)Nb0.02O3 ceramics
文献类型：期刊论文
| 作者 | Li, Song1; Nie, Hengchang; Chen, Xuefeng; Cao, Fei; Wang, Genshui; Dong, Xianlin |
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| 出版日期 | 2018 |
| 卷号 | 732页码:306 |
| 关键词 | Ferroelectric Ceramics Antiferroelectricity X-ray diffraction Phase transition |
| ISSN号 | 0925-8388 |
| DOI | 10.1016/j.jallcom.2017.10.184 |
| 英文摘要 | Pb-0.99(SnxZr0.95-xTi0.05)(0.98)Nb0.02O3 (PNZST(x), 0.10 <= x <= 0.18) ceramics were fabricated by conventional solid state reaction method. Effects of tin (Sn) doping and its content x on their structure, phase transition behavior, and electrical properties were investigated. Analysis of X-ray diffraction patterns and Rietveld refinement results confirmed the crystal structures of different phases and also compositional driven phase transitions. The results indicated that with the increase in the value of x, orthorhombic phase was transformed into distorted tetragonal phase through rhombohedral phase. Ceramics exhibited the orthorhombic-rhombohedral phase coexistence for 0.10 <= x <= 0.16, and orthorhombic -rhombohedral-distorted tetragonal multiphase coexistence for x = 0.18. Although the orthorhombic antiferroelectric (AFE) phase was the major phase, no double hysteresis loops were detected through electrical hysteresis loop measurements because the electric field-induced AFE to ferroelectric (FE) phase transition occurred under the applied electric field, and the induced FE phase could not reverse back to AFE state after the removal of electric field. However, the trace of AFE behavior could be observed at a lower testing electric field. Moreover, increasing Sn content led to linear increment in phase transition temperature of FERL-FERH, up to 98.7 degrees C for x - 0.18. (C) 2017 Elsevier B.V. All rights reserved. |
| 学科主题 | Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
| WOS记录号 | WOS:000415931900038 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | This work was supported by the National Nature Science Foundation of China (51202273 and U1330128), and Chinese Academy of Sciences Research Equipment Development Project (No. YZ201332). ; This work was supported by the National Nature Science Foundation of China (51202273 and U1330128), and Chinese Academy of Sciences Research Equipment Development Project (No. YZ201332). |
| 源URL | [http://ir.sic.ac.cn/handle/331005/24539]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Inorgan Funct Mat & Devices, Shanghai Inst Ceram, 1295 Dingxi Rd, Shanghai 200050, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Song,Nie, Hengchang,Chen, Xuefeng,et al. Structure, phase transition behavior, and electrical properties of Pb-0.99(SnxZr0.95-xTi0.05)(0.98)Nb0.02O3 ceramics[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2018,732:306, 313. |
| APA | Li, Song,Nie, Hengchang,Chen, Xuefeng,Cao, Fei,Wang, Genshui,&Dong, Xianlin.(2018).Structure, phase transition behavior, and electrical properties of Pb-0.99(SnxZr0.95-xTi0.05)(0.98)Nb0.02O3 ceramics.JOURNAL OF ALLOYS AND COMPOUNDS,732,306. |
| MLA | Li, Song,et al."Structure, phase transition behavior, and electrical properties of Pb-0.99(SnxZr0.95-xTi0.05)(0.98)Nb0.02O3 ceramics".JOURNAL OF ALLOYS AND COMPOUNDS 732(2018):306. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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