Simultaneously high-energy storage density and responsivity in quasi-hysteresis-free Mn-doped Bi0.5Na0.5TiO3-BaTiO3-(Sr0.7Bi0.20.1 )TiO3 ergodic relaxor ceramics
文献类型:期刊论文
作者 | Li, Feng1,2; Zhai, Jiwei; Shen, Bo; Liu, Xing; Zeng, Huarong1 |
刊名 | MATERIALS RESEARCH LETTERS
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出版日期 | 2018 |
卷号 | 6期号:7页码:345 |
关键词 | Bi0.5Na0.5TiO3 energy storage defect complex quasi-hysteresis-free |
ISSN号 | 2166-3831 |
DOI | 10.1080/21663831.2018.1457095 |
英文摘要 | High-energy storage density, responsivity and efficiency, i.e. W-R = 1.07 J/cm(3), pound = 119J/(kV m(2)) and eta = 92%, were simultaneously obtained in Mn-doped 0.62Bi(0.5)Na(0).5TiO3-0.06BaTiO(3)-0.32 (Sr0.7Bi0.20.1)TiO3 ergodic relaxor ceramics. Appropriate Mn doping was beneficial to enhance breakdown field strength. Moreover, temperature and different atmosphere-dependent impedance spectroscopy results indicated that oxygen vacancies were the conductivity mechanism for all samples. The valence state of Mn together with the conjugation between Mn ion and oxygen vacancies was confirmed by X-ray photoelectron spectra and electric paramagnetic resonance. The above results indicate that quasi-hysteresis-free loops with high-energy storage performances can be obtained by the induced defect complex. [GRAPHICS] IMPACT STATEMENT High-energy storage density W-R = 1.07J/cm(3), responsivity 5 = 119J/(kVm(2)) and efficiency eta = 92% were simultaneously obtained in quasi-hysteresis-free ceramics by introducing defect complex. |
学科主题 | Materials Science, Multidisciplinary |
WOS记录号 | WOS:000432344200001 |
出版者 | TAYLOR & FRANCIS INC |
资助机构 | This work was supported the Ministry of Science and Technology of China through the 973-Project under grant [2015CB654601], National Key R&D Program of China [2016YFA0201103] and the Instrument Developing Project of Chinese Academy of Sciences [ZDKYYQ20180004]. ; This work was supported the Ministry of Science and Technology of China through the 973-Project under grant [2015CB654601], National Key R&D Program of China [2016YFA0201103] and the Instrument Developing Project of Chinese Academy of Sciences [ZDKYYQ20180004]. |
源URL | [http://ir.sic.ac.cn/handle/331005/24573] ![]() |
专题 | 中国科学院上海硅酸盐研究所 |
作者单位 | 1.Tongji Univ, Sch Mat Sci Engn, Key Lab Adv Civil Engn Mat, Funct Mat Res Lab,Minist Educ, 4800 Caoan Rd, Shanghai 201804, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Inorgan Funct Mat & Devices, Shanghai 200050, Peoples R China 3.Univ Chinese Acad Sci, Beijing, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Feng,Zhai, Jiwei,Shen, Bo,et al. Simultaneously high-energy storage density and responsivity in quasi-hysteresis-free Mn-doped Bi0.5Na0.5TiO3-BaTiO3-(Sr0.7Bi0.20.1 )TiO3 ergodic relaxor ceramics[J]. MATERIALS RESEARCH LETTERS,2018,6(7):345, 352. |
APA | Li, Feng,Zhai, Jiwei,Shen, Bo,Liu, Xing,&Zeng, Huarong.(2018).Simultaneously high-energy storage density and responsivity in quasi-hysteresis-free Mn-doped Bi0.5Na0.5TiO3-BaTiO3-(Sr0.7Bi0.20.1 )TiO3 ergodic relaxor ceramics.MATERIALS RESEARCH LETTERS,6(7),345. |
MLA | Li, Feng,et al."Simultaneously high-energy storage density and responsivity in quasi-hysteresis-free Mn-doped Bi0.5Na0.5TiO3-BaTiO3-(Sr0.7Bi0.20.1 )TiO3 ergodic relaxor ceramics".MATERIALS RESEARCH LETTERS 6.7(2018):345. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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